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DIETHYL (CHLOROMETHYL)PHOSPHONATE

DIETHYL (CHLOROMETHYL)PHOSPHONATE Structure
DIETHYL (CHLOROMETHYL)PHOSPHONATE
  • CAS No.3167-63-3
  • Chemical Name:DIETHYL (CHLOROMETHYL)PHOSPHONATE
  • CBNumber:CB7297881
  • Molecular Formula:C5H12ClO3P
  • Formula Weight:186.57
  • MOL File:3167-63-3.mol
DIETHYL (CHLOROMETHYL)PHOSPHONATE Property
  • Boiling point 109-110 °C10 mm Hg(lit.)
  • Density 1.2 g/mL at 25 °C(lit.)
  • refractive index n20/D 1.437(lit.)
  • Flash point 188 °F
  • storage temp. 2-8°C
  • solubility sol THF, ether, dichloromethane, chloroform
  • form Liquid
  • color Clear colorless to light yellow
  • Specific Gravity 1.2
  • BRN 1363361
  • FDA UNII H3LYK2K3U6
  • EPA Substance Registry System Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)
  • UNSPSC Code 12352101
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :26-36
  • WGK Germany  :3
  • Hazard Note  :Irritant
  • HS Code  :29319090
  • NFPA 704:
    1
    1 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P302+P352-P305+P351+P338
DIETHYL (CHLOROMETHYL)PHOSPHONATE Price More Price(3)
  • Brand: Sigma-Aldrich(India)
  • Product number: 263613
  • Product name : Diethyl chloromethylphosphonate
  • Purity: 97%
  • Packaging: 1ML
  • Price: ₹9764.15
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: D4588
  • Product name : Diethyl (Chloromethyl)phosphonate
  • Purity: min. 98.0 %
  • Packaging: 1G
  • Price: ₹6200
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: D4588
  • Product name : Diethyl (Chloromethyl)phosphonate
  • Purity: min. 98.0 %
  • Packaging: 5G
  • Price: ₹19800
  • Updated: 2022/05/26
  • Buy: Buy

DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties,Usage,Production

  • Chemical Properties Clear colorless to light yellow liquid
  • Uses Reactant involved in:
    • Subsequent alkylation after nucleophilic substitution
    • One-pot alkylation-boration of α-haloalkylphosphonates
    • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
    • Phosphorylation leading to P-containing cyclopropanes
    • Wadsworth-Emmons reactions
    • Ring expansion of zircnacycles via carbenoid insertion
  • Synthesis Reference(s) Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1
  • reaction suitability reaction type: C-C Bond Formation
  • Synthesis Diethyl (chloromethyl)phosphonate is synthesized by a preparative scale of (EtO)2P(O)CH2Cl and other (1- chloroalkyl)phosphonates is relatively difficult. Ethanolysis of (chloromethyl)phosphonic dichloride is the most general and useful procedure (eq 1). DIETHYL (CHLOROMETHYL)PHOSPHONATE synthesis route
DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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DIETHYL (CHLOROMETHYL)PHOSPHONATE Spectrum
3167-63-3, DIETHYL (CHLOROMETHYL)PHOSPHONATERelated Search:
  • Olefination
  • Horner-Wadsworth-Emmons Reagents
  • C-C Bond Formation
  • 高端化学
  • 有机化工原料
  • 其他生化试剂
  • 键形成
  • Horner-Wadsworth-Emmons Reagents
  • Synthetic Reagents
  • Olefination
  • C-C Bond Formation
  • ClCH2POOC2H52
  • C5H12ClO3P
  • 二乙基(氯甲基)膦酸酯
  • 二甲基(氯甲基)丙烯酯
  • 二甲基(氯甲基)丙烯酯 1G
  • 氯甲基磷酸二乙酯
  • 氯甲基膦酸二乙酯
  • 3167-63-3
  • Diethyl P-(chloromethyl)phosphonate
  • Diethyl (Chloromethyl)phosphonate &gt
  • Phosphonic acid P -(chloromethyl)-diethyl ester
  • 1-[chloromethyl(ethoxy)phosphoryl]oxyethane
  • Diethyl (chloromethyl)
  • Diethyl chloromethylphosphonate 97%
  • NSC 67753
  • Diethyl (chloromethyl)phosphonate,98%
  • (Chloromethyl)phosphonic acid diethyl ester
  • Diethyl(chloromethyl)phosphonate, 97 %
  • [DIETHYL-(CHLORMETHYL)]-PHOSPHONAT
  • DIETHYL (CHLOROMETHYL)PHOSPHONATE
  • (chloromethyl)-phosphonicacidiethylester

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