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3-Cyanopyridine

3-Cyanopyridine Structure
3-Cyanopyridine
  • CAS No.100-54-9
  • Chemical Name:3-Cyanopyridine
  • CBNumber:CB9852589
  • Molecular Formula:C6H4N2
  • Formula Weight:104.11
  • MOL File:100-54-9.mol
3-Cyanopyridine Property
  • Melting point: :48-52 °C(lit.)
  • Boiling point: :201 °C(lit.)
  • Density  :1.159
  • refractive index  :1.5242 (estimate)
  • Flash point: :184 °F
  • storage temp.  :Inert atmosphere,Room Temperature
  • solubility  :140g/l
  • pka :pK1:1.45(+1) (25°C)
  • form  :Crystalline Mass, Crystals or Chunks
  • color  :Colorless or white to yellow
  • Water Solubility  :140 g/L (20 ºC)
  • BRN  :107711
  • Stability: :Incompatible with strong oxidizing agents, strong reducing agents, strong acids, strong bases.
  • InChIKey :GZPHSAQLYPIAIN-UHFFFAOYSA-N
  • CAS DataBase Reference :100-54-9(CAS DataBase Reference)
  • EWG's Food Scores :1
  • FDA UNII :X64V0K6260
  • NIST Chemistry Reference :3-Pyridinecarbonitrile(100-54-9)
  • EPA Substance Registry System :3-Pyridinecarbonitrile (100-54-9)
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H335-H319-H412-H302-H315-H318
  • Precautionary statements P264-P270-P273-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501-P280-P301+P312+P330-P305+P351+P338+P310-P280h-P305+P351+P338
3-Cyanopyridine Price More Price(8)
  • Brand: Sigma-Aldrich
  • Product number: C94807
  • Product name : 3-Pyridinecarbonitrile
  • Purity: 98%
  • Packaging: 100g
  • Price: $30
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: C94807
  • Product name : 3-Pyridinecarbonitrile
  • Purity: 98%
  • Packaging: 5g
  • Price: $22.4
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: C0456
  • Product name : 3-Cyanopyridine
  • Purity: >98.0%(GC)
  • Packaging: 25g
  • Price: $18
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: C0456
  • Product name : 3-Cyanopyridine
  • Purity: >98.0%(GC)
  • Packaging: 500g
  • Price: $70
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Alfa Aesar
  • Product number: A14850
  • Product name : 3-Cyanopyridine, 98%
  • Purity: 
  • Packaging: 500g
  • Price: $88.5
  • Updated: 2021/03/22
  • Buy: Buy

3-Cyanopyridine Chemical Properties,Usage,Production

  • Chemical Properties white to beige solid
  • Chemical Properties The cyanopyridines are as follows: 2-cyano-: A white to tan liquid or solid. Almond odor. Boiling point=2213℃ ; freezing/melting point=27℃ ; flash point=89℃ . 3-cyano-: a colorless liquid or gray crystal- line solid.
  • Definition ChEBI: A nitrile that is pyridine substituted by a cyano group at position 3.
  • Synthesis Reference(s) Tetrahedron Letters, 29, p. 2155, 1988 DOI: 10.1016/S0040-4039(00)86697-6
  • Potential Exposure Limits in Air NIOSH IDLH525 mg/m3 NIOSH REL: (nitriles) 2 ppm, Ceiling Concentration, not to be exceeded in any 15-minute work period.
  • Shipping UN3276 Nitriles, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required, Potential Inhalation Hazard (Special Provision 5).
  • Purification Methods It is recrystallised to constant melting point from o-xylene/hexane. [Beilstein 22/2 V 115.]
  • Incompatibilities Oxidizing agents, such as perchlorates, peroxides, and permanganates. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give car- boxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids .
3-Cyanopyridine Preparation Products And Raw materials
Raw materials
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