Chemical Properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Uses
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 664, 1987
DOI: 10.1021/jo00380a031
General Description
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with
i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K
4[Fe(CN)
6] as cyanating source.
