3-Chlorophenol Structure

3-Chlorophenol

Chemical Properties

Melting point 31-34 °C (lit.)
Boiling point 214 °C (lit.)
Density  1.218 g/mL at 25 °C (lit.)
vapor pressure  1 hPa (44 °C)
refractive index  n20/D 1.563(lit.)
Flash point >230 °F
storage temp.  Store below +30°C.
solubility  Soluble in ethanol and ether.
pka 8.85(at 25℃)
form  Liquid After Melting
color  Clear yellow to brownish
PH 3.5 (27.7g/l, H2O, 20℃)
Odor distinct phenol-like odor
Relative density, gas (air=1) 1.218 g/cm3 at 25 °C
Water Solubility  27.7 g/L (20 ºC)
Merck  14,2154
BRN  1634401
Henry's Law Constant 7.2×100 mol/(m3Pa) at 25℃, Chao et al. (2017)
Stability Stable. Combustible. Incompatible with acid chlorides, oxidizing agents, acid anhydrides. Discolours in air.
InChI 1S/C6H5ClO/c7-5-2-1-3-6(8)4-5/h1-4,8H
InChIKey HORNXRXVQWOLPJ-UHFFFAOYSA-N
SMILES Oc1cccc(Cl)c1
CAS DataBase Reference 108-43-0(CAS DataBase Reference)
FDA UNII Z2Z7M2FTAD
NIST Chemistry Reference Phenol, 3-chloro-(108-43-0)
EPA Substance Registry System m-Chlorophenol (108-43-0)
UNSPSC Code 12352104
NACRES NA.22

Safety

Symbol(GHS) Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
Signal wordWarning
Hazard statements H302+H312+H332-H315-H319-H371-H341-H411
Precautionary statements P501-P273-P260-P270-P202-P201-P271-P264-P280-P391-P337+P313-P305+P351+P338-P308+P311-P362+P364-P332+P313-P301+P312+P330-P302+P352+P312-P304+P340+P312-P405
Hazard Codes  Xn,N
Risk Statements  20/21/22-51/53
Safety Statements  28-61-28A
RIDADR  UN 2020 6.1/PG 3
WGK Germany  2
RTECS  SK2450000
F  9
Autoignition Temperature >600 °C
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  III
HS Code  29081000
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 2
Eye Dam. 1
Skin Irrit. 2
Hazardous Substances Data 108-43-0(Hazardous Substances Data)
Toxicity LD50 orally in rats: 0.57 g/kg (Deichmann)
NFPA 704:
1
2 0

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