Structure
(3-Bromophenyl)thiourea, C7H7BrN2S, the thiourea moiety is nearly planar (r.m.s. deviation = 0.004 Å) and it forms a dihedral angle of 66.72 (15)° with the benzene ring. The C—N—C—N2 torsion angle is 15.1 (4)°. In the crystal, molecules are linked via N—H⋯S and N—H⋯N hydrogen bonds into sheets lying parallel to (101)[1].
References
[1] Fun, Hoong-Kun et al. “1-(3-Bromo-phen-yl)thio-urea.” Acta crystallographica. Section E, Structure reports online vol. 68,Pt 8 (2012): o2462. doi:10.1107/S1600536812031601