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ETHYL 3-PHENYLGLYCIDATE

ETHYL 3-PHENYLGLYCIDATE Structure
ETHYL 3-PHENYLGLYCIDATE
  • CAS No.121-39-1
  • Chemical Name:ETHYL 3-PHENYLGLYCIDATE
  • CBNumber:CB5292099
  • Molecular Formula:C11H12O3
  • Formula Weight:192.21
  • MOL File:121-39-1.mol
ETHYL 3-PHENYLGLYCIDATE Property
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :23-24/25
  • WGK Germany  :2
  • RTECS  :MB4970000
  • TSCA  :Yes
  • HS Code  :29189990
  • Hazardous Substances Data :121-39-1(Hazardous Substances Data)
  • Toxicity :The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).
  • NFPA 704:
    1
    2 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H303-H335-H315-H319
  • Precautionary statements P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
ETHYL 3-PHENYLGLYCIDATE Price More Price(8)
  • Brand: Sigma-Aldrich
  • Product number: 291404
  • Product name : Ethyl 3-phenylglycidate
  • Purity: technical grade, 92%, mixture of
  • Packaging: 100ml
  • Price: $42
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: W245402
  • Product name : Ethyl 3-phenylglycidate
  • Purity: mixture of
  • Packaging: sample
  • Price: $50
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: E0798
  • Product name : Ethyl 3-Phenylglycidate (cis- and trans- mixture)
  • Purity: >90.0%(GC)
  • Packaging: 25g
  • Price: $20
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Alfa Aesar
  • Product number: B22990
  • Product name : Ethyl 3-phenylglycidate, cis + trans, 90+%
  • Purity: 
  • Packaging: 50ml
  • Price: $26.5
  • Updated: 2020/06/24
  • Buy: Buy
  • Brand: Alfa Aesar
  • Product number: B22990
  • Product name : Ethyl 3-phenylglycidate, cis + trans, 90+%
  • Purity: 
  • Packaging: 250ml
  • Price: $70
  • Updated: 2020/06/24
  • Buy: Buy

ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Usage,Production

  • Chemical Properties pale yellow liquid
  • Chemical Properties Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
    It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.
  • Chemical Properties Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.
  • Occurrence Apparently has not been reported to occur in nature.
  • Preparation Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.
  • Aroma threshold values Detection: 8.5 ppm
  • Taste threshold values Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.
  • Synthesis Reference(s) Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010
  • General Description Clear pale yellow or yellow liquid.
  • Air & Water Reactions Slightly water soluble.
  • Reactivity Profile Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
  • Fire Hazard ETHYL 3-PHENYLGLYCIDATE is probably combustible.
  • Safety Profile Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
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121-39-1, ETHYL 3-PHENYLGLYCIDATERelated Search:
  • (2R,3R)-3-Phenyloxirane-2-carboxylic acid ethyl ester
  • 3-Phenyloxirane-2-carboxylic acid ethyl ester
  • Ethyl 3-Phenylglycidate (cis- and trans- mixture)
  • (2S,3S)-3-Phenyloxirane-2-carboxylic acid ethyl ester
  • Ethyl 3-phenylglycidate,98%,mixture of cis and trans
  • Ethyl 3-phenylglycidate,90%,mixture of cis and trans
  • ethyl2,3-epoxy-3-phenylpropion
  • Ethyl 2,3-epoxy-3-phenylpropionate
  • Ethyl 3-phenyl-2-oxiranecarboxylate
  • Ethyl alpha,beta-epoxy-alpha-phenylpropionate
  • Ethyl alpha,beta-epoxyhydrocinnamate
  • ethyl2,3-epoxy-3-phenylpropionate
  • ethyl3-phenylglycidate,mixtureofcisandtrans
  • ethyl3-phenyloxirane
  • ethyl3-phenyloxirane-2-
  • ethyl3-phenyloxirane-2-carboxylate
  • ethyl3-phenyloxiranecarboxylate
  • ethylalpha,beta-epoxy-alpha-phenylpropionate
  • ethylalpha,beta-epoxyhydrocinnamate
  • Oxiranecarboxylicacid,3-phenyl-,ethylester
  • 3-Phenylglycidic Acid Ethyl Ester Ethyl 3-Phenyloxiranecarboxylate
  • Ethyl 3-Phenylglycidate&nbsp
  • Ethyl 3-Phenylglycidate (<i>cis</i>- and <i>trans</i>- mixture)
  • 3-phenyl-glycidicaciethylester
  • 3-phenyl-oxiranecarboxylicaciethylester
  • GLYCIDIC ACID, 3-PHENYL:ETHYL ESTER
  • ETHYL 3-PHENYLGLYCIDATE
  • FEMA 2454
  • ETHYL PHENYLGLYCIDATE
  • ETHYL A B-EPOXYHYDROCINNAMATE
  • ETHYL3-PHENYLGLYCIDATE,TECHNICAL
  • 23EPOXY3PHENYLPROPIONICACIDETHYLESTERCISTRANS
  • Ethyl-3-phenyloxiran-2-carboxylat
  • Ethyl 3-phenylglycidate, cis + trans, 90+%
  • ETHYL PHENYLGLYCIDATE FCC
  • 3-PHENYLGLYCIDIC ACID ETHYL ESTER
  • 3-PHENYLOXIRANECARBOXYLIC ACID ETHYL ESTER
  • ETHYL 3-PHENYLGLYCIDATE 92+% &
  • ETHYL 3-PHENYLGLYCIDATE, TECH., 92%, MIX TURE OF CIS AND TRANS
  • Ethyl 3-phenylglycidate, cis + trans, 95%
  • Ethyl3-Phenylglycidate(cis-andtrans-mixture)&gt
  • 2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester
  • ETHYL 3-PHENYLGLYCIDATE USP/EP/BP
  • strawberry glycidate 2
  • 121-39-1
  • C11H12O3C11H12O3C11H12O3C11H12O3C11H12O3
  • Oxygen Compounds
  • Organic Building Blocks
  • Epoxides
  • Building Blocks
  • Alphabetical Listings
  • E-F
  • Flavors and Fragrances
  • Epoxides
  • Organic Building Blocks
  • Oxygen Compounds
  • Building Blocks
  • Chemical Synthesis