ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98

Reaction

1. Catalyst for the cross-coupling of aryl chlorides with boronic acids.
2. Catalyst for the diamination of conjugated dienes and trienes.
3. Catalyst for the dehalogenation of aryl chlorides.
4. Catalyst for anaerobic alcohol oxidation.
5. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. 

Chemical Properties

Yellow crystal

Uses

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.

General Description

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst