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Butanethiol Structure

Butanethiol

Chemical Properties

Melting point −116 °C(lit.)
Boiling point 98 °C(lit.)
Density  0.842 g/mL at 25 °C(lit.)
vapor density  3.1 (vs air)
vapor pressure  83 mm Hg ( 37.7 °C)
FEMA  3478 | 1-BUTANETHIOL
refractive index  n20/D 1.443(lit.)
Flash point 55 °F
storage temp.  Store below +30°C.
solubility  Slightly soluble in water, soluble in alcohol and oils.
pka 11.51 at 25 °C (23.0% aqueous tert-butyl alcohol, Friedman et al., 1965)
form  Liquid
color  Colorless
Specific Gravity 0.842
Odor Strong skunk-like.
explosive limit 1.4-11.3%(V)
Odor Type sulfurous
Odor Threshold 0.0000028ppm
Water Solubility  0.60 g/100 mL. Slightly soluble
Sensitive  Air Sensitive
Merck  14,1577
JECFA Number 511
BRN  1730908
Henry's Law Constant (x 10-3 atm?m3/mol): 7.04 at 20 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits NIOSH REL: 15-min ceiling 0.5 ppm (1.8 mg/m3), IDLH 500 ppm; OSHA PEL: TWA 10 ppm (35 mg/m3); ACGIH TLV: TWA 0.5 ppm (adopted).
Dielectric constant 4.9500000000000002
Stability Stable. Incompatible with oxidizing agents, bases, alkali metals. Highly flammable. May discolour on exposure to air.
LogP 2.28
Substances Added to Food (formerly EAFUS) 1-BUTANETHIOL
CAS DataBase Reference 109-79-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 77OY909F30
NIST Chemistry Reference 1-Butanethiol(109-79-5)
EPA Substance Registry System Butyl mercaptan (109-79-5)

Safety

Symbol(GHS)
Signal wordDanger
Hazard statements H225-H302+H332-H315-H317-H319-H335
Precautionary statements P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P305+P351+P338
Hazard Codes  F,Xn
Risk Statements  11-20/22-36/37/38-21/22-43
Safety Statements  16-23-26-36-9-36/37-33-37-37/39
RIDADR  UN 2347 3/PG 2
OEL Ceiling: 0.5 ppm (1.8 mg/m3) [15-minute]
WGK Germany  3
RTECS  EK6300000
10-13-23
TSCA  Yes
HS Code  2930 90 98
HazardClass  3
PackingGroup  II
Hazardous Substances Data 109-79-5(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 1500 mg/kg
IDLA 500 ppm
NFPA 704:
3
1 0

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Butanethiol Chemical Properties,Usage,Production

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