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4,4'-Methylene bis(2-chloroaniline) Structure

4,4'-Methylene bis(2-chloroaniline)

Chemical Properties

Melting point 102-107 °C(lit.)
Boiling point 202-214 °C0.3 mm Hg(lit.)
Density  1.44
vapor pressure  0.001Pa at 20℃
refractive index  1.6710 (estimate)
Flash point >230 °F
solubility  Acetonitrile (Slightly), DMSO (Slightly), Methanol (Slightly)
pka 3.33±0.25(Predicted)
color  Light orange to Yellow to Green
Water Solubility  <0.1 g/100 mL at 25 ºC
Merck  14,6059
BRN  1882318
Stability Stable, but decomposes exothermically, and possibly explosively, above 200 C. Incompatible with strong oxidizing agents.
InChIKey IBOFVQJTBBUKMU-UHFFFAOYSA-N
LogP 2.5 at 25℃
CAS DataBase Reference 101-14-4(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances 4,4'-METHYLENEBIS(2-CHLOROANILINE)--PROHIBITED
FDA UNII 3L2W5VTT2A
IARC 1 (Vol. Sup 7, 57, 99, 100F) 2012
NIST Chemistry Reference Aniline), methylene bis-4,4'-(2-chloro-(101-14-4)
EPA Substance Registry System 4,4'-Methylenebis(2-chloroaniline) (101-14-4)

Safety

Symbol(GHS)
Signal wordDanger
Hazard statements H302-H341-H350-H410
Precautionary statements P201-P273-P301+P312+P330-P308+P313
Hazard Codes  T,N
Risk Statements  45-22-50/53-53-50-68
Safety Statements  53-45-60-61-36/37
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  CY1050000
HazardClass  6.1(b)
PackingGroup  III
HS Code  29215900
Hazardous Substances Data 101-14-4(Hazardous Substances Data)
Toxicity LD50 oral in rat: 1140mg/kg
NFPA 704:
1
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4,4'-Methylene bis(2-chloroaniline) Chemical Properties,Usage,Production

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