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Dimethyl adipate

Dimethyl adipate Structure
Dimethyl adipate
  • CAS No.627-93-0
  • Chemical Name:Dimethyl adipate
  • CBNumber:CB1412954
  • Molecular Formula:C8H14O4
  • Formula Weight:174.19
  • MOL File:627-93-0.mol
Dimethyl adipate Property
  • Melting point: :8 °C(lit.)
  • Boiling point: :109-110 °C14 mm Hg(lit.)
  • Density  :1.062 g/mL at 20 °C(lit.)
  • vapor pressure  :0.2 mm Hg ( 20 °C)
  • refractive index  :n20/D 1.428(lit.)
  • FEMA  :4472 | DIMETHYL ADIPATE
  • Flash point: :225 °F
  • storage temp.  :Store below +30°C.
  • solubility  :<1g/l
  • form  :Liquid
  • color  :Clear
  • explosive limit :0.81-8.1%(V)
  • Water Solubility  :Miscible with alcohols and ether. Immiscible with water.
  • JECFA Number :1964
  • Merck  :14,162
  • BRN  :1707443
  • Stability: :Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases reducing agents.
  • InChIKey :UDSFAEKRVUSQDD-UHFFFAOYSA-N
  • CAS DataBase Reference :627-93-0(CAS DataBase Reference)
  • Substances Added to Food (formerly EAFUS) :DIMETHYL ADIPATE
  • EWG's Food Scores :1
  • FDA UNII :BY71RX0R62
  • NIST Chemistry Reference :Hexanedioic acid, dimethyl ester(627-93-0)
  • EPA Substance Registry System :Dimethyl adipate (627-93-0)
Safety
  • Safety Statements  :24/25
  • WGK Germany  :1
  • RTECS  :AV1645000
  • Autoignition Temperature :680 °F
  • TSCA  :Yes
  • HS Code  :29171290
  • Hazardous Substances Data :627-93-0(Hazardous Substances Data)
  • Toxicity :LD50 orally in Rabbit: 8191 mg/kg LD50 dermal Rabbit > 2250 mg/kg
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal word
  • Hazard statements
  • Precautionary statements
Dimethyl adipate Price More Price(9)
  • Brand: Sigma-Aldrich
  • Product number: 186252
  • Product name : Dimethyl adipate
  • Purity: ≥99%
  • Packaging: 100g
  • Price: $32.5
  • Updated: 2019/12/02
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 186252
  • Product name : Dimethyl adipate
  • Purity: ≥99%
  • Packaging: 500g
  • Price: $81.9
  • Updated: 2019/12/02
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: A0166
  • Product name : Dimethyl Adipate
  • Purity: >99.0%(GC)
  • Packaging: 25mL
  • Price: $16
  • Updated: 2019/12/02
  • Buy: Buy
  • Brand: TCI Chemical
  • Product number: A0166
  • Product name : Dimethyl Adipate
  • Purity: >99.0%(GC)
  • Packaging: 500mL
  • Price: $41
  • Updated: 2019/12/02
  • Buy: Buy
  • Brand: Alfa Aesar
  • Product number: B21174
  • Product name : Dimethyl adipate, 99%
  • Purity: 
  • Packaging: 250g
  • Price: $24.9
  • Updated: 2019/12/02
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Dimethyl adipate Chemical Properties,Usage,Production

  • Description Dimethyl adipate (DMA) is a colourless and flammable liquid. It is soluble in alcohol and ether but sparingly soluble in water. DMA is incompatible with strong oxidising agents, and on decomposition, it emits carbon monoxide, irritating and toxic fumes and gases, and carbon dioxide. DMA reacts with acids, alkalis, and strong oxidants. DMA is synthesised by the esterification of adipic acid. DMA is part of a dibasic ester (DBE) blend used as a major ingredient in several paint strippers, and the DBE blends used in paint stripping formulations contain a major portion (about 90%) of DMA. DMA is used as a chemical intermediate (polymers, agrochemicals), cellulose resins, a speciality solvent (inks, coatings, adhesives), and an emollient and can also be utilised as a paint remover and plasticiser.
  • Chemical Properties Dimethyl adipate (DMA) is a colorless and flammable liquid. It is soluble in alcohol and ether, but sparingly soluble in water. It reacts with acids, alkalis, and strong oxidants. Dimethyl adipate is synthesized by the esterifi cation of adipic acid. Dimethyl adipate is part of a dibasic ester (DBE) blend used as a major ingredient in several paint strippers; the DBE blends used in paint stripping formulations contain a major portion (about 90%) of DMA. Dimethyl adipate is used as a chemical intermediate and as a plasticizer in the production of paper and cellulose resins.
  • Chemical Properties colourless liquid
  • Uses It is used as a plasticizer for cellulose-type resins and a finish remover.
  • Production Methods Dimethyl adipate is manufactured via esterification of adipic acid and methanol in the presence of an acid catalyst.
  • General Description Colorless liquid.
  • Air & Water Reactions Flammable. Hydrolyzed by strong mineral acids and strong alkalis.
  • Reactivity Profile Dimethyl adipate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
  • Health Hazard May be harmful by inhalation, ingestion, or skin absorption. May cause irritation.
  • Health Hazard Exposures to dimethyl adipate cause toxicity and adverse health effects in laboratory animals and humans. Workplace exposures to dimethyl adipate by inhalation, ingestion, or skin absorption cause harmful and irritation effects to users.
  • Safety Profile Moderately toxic by intraperitoneal route. Experimental teratogenic and reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
  • Carcinogenicity In a chronic inhalation toxicity study of dimethyl adipate, groups of male and female rats were exposed to 400 mg/m3 of dimethyl adipate over a 90-day period. Focal respiratory metaplasia of the olfactory epithelium was found. These nonneoplastic lesions were minimal to mild in severity .
  • Precautions During handling of dimethyl adipate, occupational workers should be careful and use self-contained breathing apparatus, rubber boots, and heavy rubber gloves and avoid prolonged period of exposures. Workers should avoid contact of dimethyl adipate with skin, eyes and nose.
Dimethyl adipate Preparation Products And Raw materials
Raw materials
Preparation Products
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