Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy

Reaction

1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.