Uses
Electrochemically inactive [Mg
2(μ-Cl)
3.6THF][C
2H
5AlCl
3] crystal may be obtained from an electrolyte composed of Di-
n-butylmagnesium and ethylaluminum dichloride. Di-
n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS
2 or WO
2Cl
2. Interaction of lithium alkoxide with di-
n-butylmagnesium was investigated.
Application
Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand.