Selenoharnstoff

Bezeichnung:Selenoharnstoff

CAS-Nr630-10-4

Englisch Name:SELENOUREA

CBNumberCB9309553

SummenformelCH4N2Se

Molgewicht123.02

MOL-Datei630-10-4.mol

Synonyma

Selenoharnstoff

Selenoharnstoff physikalisch-chemischer Eigenschaften

Schmelzpunkt	210-215 °C (dec.)
Siedepunkt	200°C (rough estimate)
storage temp.	2-8°C
Löslichkeit	DMSO (Slightly, Heated)
Aggregatzustand	solid
Farbe	pink
Wasserlöslichkeit	Soluble in water, alcohol and ether.
Sensitive	Air & Moisture Sensitive
BRN	1734744
Expositionsgrenzwerte	ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
InChI	InChI=1S/CH4N2Se/c2-1(3)4/h(H4,2,3,4)
InChIKey	IYKVLICPFCEZOF-UHFFFAOYSA-N
SMILES	NC(N)=[Se]
CAS Datenbank	630-10-4(CAS DataBase Reference)
EPA chemische Informationen	Selenourea (630-10-4)

Sicherheit

Kennzeichnung gefährlicher	T,N
R-Sätze:	23/25-33-50/53
S-Sätze:	20/21-28-45-60-61
RIDADR	UN 3283 6.1/PG 2
WGK Germany	3
RTECS-Nr.	YU1820000
F	8-10-23
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	II
HS Code	29310099
Speicherklasse	6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
Hazard Classifications	Acute Tox. 2 Oral Acute Tox. 3 Inhalation Aquatic Acute 1 Aquatic Chronic 1 STOT RE 2
Giftige Stoffe Daten	630-10-4(Hazardous Substances Data)

Gefahreninformationscode (GHS)

SELENOUREA Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R23/25:Giftig beim Einatmen und Verschlucken.
R33:Gefahr kumulativer Wirkungen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S20/21:Bei der Arbeit nicht essen, trinken,rauchen.
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
slightly pink to grey crystalline needles
Verwenden
Selenourea is used in the synthesis of selenium heterocycles, which exhibit anti-inflammatory and anti-tumor activity. It acts as an effective ligand and form complexes with transition metals and metalloids.
Definition
ChEBI: Selenourea is a member of ureas and a one-carbon compound. It is functionally related to a urea.
Allgemeine Beschreibung
Solid.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Brandgefahr
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Sicherheitsprofil
Poison by ingestion and intravenous routes. When heated to decomposition it emits very toxic fumes of NO, and Se. See also SELENIUM COMPOUNDS
läuterung methode
Recrystallise it from the least volume of H2O using Norite (preferably under N2) to form colourless needles which are dried over P2O5. It is air and light sensitive. It slowly turns moderately dark on storage even below 0o. [King & Hlavacek J Am Chem Soc 73 1864 1951, Dunbar & Painter J Am Chem Soc 69 1833 1947, Bacher & Bos Recl Trav Chim Pays Bas 62 580 1943, Hope Acta Chem Scand 18 1800 1964.] The Se-methyl iodide provides yellow crystals from EtOH/Et2O with m 187-188o(dec). The N,N-dimethyl derivative crystallises from H2O or EtOH as colourless needles which slowly turn pink, then gray on standing, and although slightly soluble in *benzene it can be recrystallised from it and has m 167-170o(dec) [Zingaro et al. J Org Chem 18 292 1953, IR: Jensen & Nielsen Acta Chem Scand 20 597 1966, Beilstein 3 IV 435.]

SELENOUREA Upstream-Materialien And Downstream Produkte

Selenoharnstoff Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

630-10-4, SELENOUREA Verwandte Suche:

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