Ethylmethylsulfid

Bezeichnung:Ethylmethylsulfid

Englisch Name:Methylthioethane

CBNumberCB9151655

SummenformelC3H8S

Molgewicht76.16

Synonyma

Ethylmethylsulfid

Ethylmethylsulfid physikalisch-chemischer Eigenschaften

Schmelzpunkt	-106 °C (lit.)
Siedepunkt	66-67 °C (lit.)
Dichte	0.842 g/mL at 25 °C (lit.)
Dampfdruck	272 mm Hg ( 37.7 °C)
Brechungsindex	n20/D 1.440(lit.)
FEMA	3860 \| METHYL ETHYL SULFIDE
Flammpunkt	5 °F
storage temp.	Flammables area
Aggregatzustand	liquid
Wichte	0.842
Farbe	Colorless to Light yellow
Geruch (Odor)	at 0.10 % in propylene glycol. sulfury garlic tomato coffee pyridene cabbage vegetable meaty
Geruchsart	sulfurous
Odor Threshold	0.00023ppm
Wasserlöslichkeit	Miscible with alcohols and oils. Immiscible with water.
JECFA Number	453
BRN	1696871
LogP	1.54
CAS Datenbank	624-89-5(CAS DataBase Reference)
NIST chemische Informationen	Ethane, (methylthio)-(624-89-5)
EPA chemische Informationen	Ethyl methyl sulfide (624-89-5)

Sicherheit

Kennzeichnung gefährlicher	F
R-Sätze:	11
S-Sätze:	16-23-24/25
RIDADR	UN 1993 3/PG 2
WGK Germany	3
F	13
TSCA	Yes
HazardClass	3
PackingGroup	II
HS Code	29309090

Gefahreninformationscode (GHS)

R-Sätze Betriebsanweisung:
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
clear colorless liquid
Chemische Eigenschaften
Methyl ethyl sulfide has a cabbage-like odor.
Occurrence
Reported found in tomato, cooked chicken, beef and pork, rum, bourbon, whiskey, cocoa and coffee
Verwenden
Ethyl Methyl Sulfide is used as a corrosion inhibitor for zinc metal which finds wide applications like electrode material in batteries, sacrificial anodes and metallic coatings. It is used in mixtures designed to odorize natural gas and is made to by-pass injection system.
Aroma threshold values
Aroma characteristics at 0.1%: sulfurous, tomato and cabbage vegetative with dimethyl sulfide, meaty and metallic nuances.
Taste threshold values
Taste characteristics at 0.25 to 2 ppm: sulfurous, vegetative, dimethyl sulfide-like sweet corn notes, eggy, meaty and clam nuances
Allgemeine Beschreibung
Microwave spectra of the trans isomer of ethyl methyl sulfide and its 10 isotopic species has been investigated. Chlorination of ethyl methyl sulfide with N-chlorosuccinimide and sulfuryl chloride has been reported.