1,6-Dibromopyrene

Bezeichnung:1,6-Dibromopyrene

CAS-Nr27973-29-1

Englisch Name:1,6-Dibromopyrene

CBNumberCB8947912

SummenformelC16H8Br2

Molgewicht360.04

MOL-Datei27973-29-1.mol

1,6-Dibromopyrene physikalisch-chemischer Eigenschaften

Schmelzpunkt	228.0 to 232.0 °C
Siedepunkt	469.6±18.0 °C(Predicted)
Dichte	1.852±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
Löslichkeit	Chloroform (Very Slightly, Heated), Methanol (Very Slightly, Heated)
Aggregatzustand	Solid
Farbe	White to Off-White
maximale Wellenlänge (λmax)	246nm(EtOH)(lit.)
InChI	InChI=1S/C16H8Br2/c17-13-8-4-10-2-6-12-14(18)7-3-9-1-5-11(13)16(10)15(9)12/h1-8H
InChIKey	JRCJYPMNBNNCFE-UHFFFAOYSA-N
SMILES	C1(Br)=C2C3=C4C(C=C2)=CC=C(Br)C4=CC=C3C=C1

Sicherheit

R-Sätze:	36/37/38
S-Sätze:	26-36/37/39
HS Code	29039990

Gefahreninformationscode (GHS)

1,6-Dibromopyrene Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung
1, 6-dibromopyrene is a kind of pyrene chemical. It is majorly used as organic intermediate, OLED (organic light-emitting diodes) materials and photoelectric material. It, together with its 1, 8- isomer, can be produced by the double bromination of pyrene with bromine. It can be applied to the synthesis of bipyridine and terpyridine based ruthenium metallosynthons.
Chemische Eigenschaften
white powder
Verwenden
1,6-Dibromopyrene is an important intermediate for the synthesis of perylene diimide (PDI) derivative host structures. Perylene diimide derivatives are one of several important classes of discotic liquid crystal molecules.
Synthese
Specifically, pyrene (12.2g, 60 mmol) and 300 ml carbon tetrachloride are placed into a three-necked flask with a dropping funnel. Under room temperature, stirring, and nitrogen protection, bromine (11.5ml, 0.23mol) is dissolved in 50ml carbon tetrachloride, and then the solution is added to the reactor (the molar ratio of pyrene to bromine is 1:3.83). The mixed reaction solution is stirred at room temperature for 59 hours, then filtered, and the crude product is washed three times with 100ml methanol. The crude product is recrystallized with a mixed solvent of 260ml carbon tetrachloride and tetrahydrofuran to obtain 19.77g of pure 1,6-dibromopyrene, with a yield of 90.9% and a purity of 99.8%.
Einzelnachweise
Goze, Christine, et al. "Synthesis of bipyridine and terpyridine based ruthenium metallosynthons for grafting of multiple pyrene auxiliaries."Tetrahedron letters 44.48 (2003): 8713-8716.
Kaplunov, Mikhail G., et al. "Novel 1, 8-bis(diarylamino)pyrenes as OLED materials." Mendeleev Communications 26.5(2016):437-439.
Gong, Xiaojie, et al. "Two Symmetrically Bis‐substituted Pyrene Derivatives: Synthesis, Photoluminescence, and Electroluminescence." Chinese Journal of Chemistry 33.8 (2015): 967-973.

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