(8S)-8α,13β-Dihydroxyserratinane-5-one

(8S)-8α,13β-Dihydroxyserratinane-5-one Chemische Eigenschaften,Einsatz,Produktion Methoden

• Beschreibung

  A further alkaloid present in Lycopodium serratum Thunb. vaT. thunbergii Mak. The base crystallizes from Me₂CO in colourless prisms and has [α]⁸_D - 27.8° (c 1.44, EtOH). Two non-phenolic hydroxyl groups are present and the alkaloid forms the 8-0-acetate, m.p. 244-5°C; the l3-0-acetate, m.p. 240-2°C and the di-O-acetate, m.p. 1 57-8°C. The tetracyc1ic structure has been proposed on the basis of the mass spectra of the alkaloid and a tentative biogenesis from lycodoline-type alkaloids also proposed.

• Einzelnachweise

  Inubushi et al., Tetrahedron Lett., 1537 (1966)
  Mass spectra:
  Inubishietal., Tetrahedron, 24,3541 (1968)
  Stereochemistry :
  Inubushi et al., Tetrahedron Lett., 1551 (1966)
  Biosythesis:
  Inubushi et aI., Chem. Pharm. Bull. (Tokyo), 16,92 (1968)

(8S)-8α,13β-Dihydroxyserratinane-5-one Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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