Methylcyclohexan

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H225：Flüssigkeit und Dampf leicht entzündbar.

  H304：Kann bei Verschlucken und Eindringen in die Atemwege tödlich sein.

  H315：Verursacht Hautreizungen.

  H336：Kann Schläfrigkeit und Benommenheit verursachen.

  H410：Sehr giftig für Wasserorganismen mit langfristiger Wirkung.

• Sicherheit

  P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

  P233：Behälter dicht verschlossen halten.

  P273：Freisetzung in die Umwelt vermeiden.

  P301+P310：BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

  P303+P361+P353：BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.

  P331：KEIN Erbrechen herbeiführen.

Methylcyclohexane Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• PHYSIKALISCHE GEFAHREN

  Die Dämpfe sind schwerer als Luft und können sich am Boden ausbreiten. Fernzündung möglich. Fließen, Schütten o.ä. kann zu elektrostatischer Aufladung führen.

• CHEMISCHE GEFAHREN

  Reagiert sehr heftig mit starken Oxidationsmitteln. Feuer- und Explosionsgefahr.

• ARBEITSPLATZGRENZWERTE

  TLV: 400 ppm (als TWA); (ACGIH 2005).
  MAK: 200 ppm 810 mg/m? Spitzenbegrenzung: überschreitungsfaktor II(2); Schwangerschaft: Gruppe D; (DFG 2008).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation der Dämpfe und durch Verschlucken.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen und die Haut. Verschlucken kann zur Aufnahme in der Lunge führen; Gefahr der Aspirationspneumonie. Möglich sind Auswirkungen auf das Zentralnervensystem. Exposition kann Bewusstseinstrübung verursachen.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Die Flüssigkeit entfettet die Haut.

• LECKAGE

  Belüftung. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit trockenem Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe.

• R-Sätze Betriebsanweisung:

  R11:Leichtentzündlich.
  R38:Reizt die Haut.
  R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
  R65:Gesundheitsschädlich: kann beim Verschlucken Lungenschäden verursachen.
  R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.

• S-Sätze Betriebsanweisung:

  S9:Behälter an einem gut gelüfteten Ort aufbewahren.
  S16:Von Zündquellen fernhalten - Nicht rauchen.
  S33:Maßnahmen gegen elektrostatische Aufladungen treffen.
  S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
  S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ärztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.

• Beschreibung

  Methylcyclohexane, an alkene, is a colorless liquid with a faint benzene-like odor. The odor thre-shold is 630 ppm (this is above the OEL). Molecularweight = 98.21; Specific gravity (H2O:1)= 0.77; Boilingpoint = 101℃; Freezing/Melting point= - 127℃; Vaporpressure= 37 mmHg at 20℃; Flash point= - 3.9℃ (cc),- 5.9℃ (oc); Autoignition temperature = 258℃. Explosivelimits: LEL= 1.2%; UEL = 6.7%. Hazard Identification(based on NFPA-704 M Rating System): Health 2,Flammability 3, Reactivity 0. Insoluble in water.

• Chemische Eigenschaften

  Methylcyclohexane, an alkene, is a colorless liquid with a faint benzene-like odor. The odor threshold is 630 ppm (this is above the OEL).

• Physikalische Eigenschaften

  Clear colorless, very flammable liquid with a faint odor similar to benzene or cyclohexane. An odor threshold concentration of 150 ppb_v was reported by Nagata and Takeuchi (1990).

• Verwenden

  Methylcyclohexane is used as a solvent and reagent in organic synthesis and polymer chemistry. It is a component of jet fuel and also used as correction fluid in certain consumer products. It acts as a starting material for toluene synthesis

• Verwenden

  Methylcyclohexane is an environmentally friendly coating, mainly used as solvent for ink, rubber, paint, varnish, oil and grease extraction solvent, chromatographic analysis standard substance, also can be used in organic synthesis and analytical reagents.

• Verwenden

  Solvent; starting material in the synthesis of toluene.

• Definition

  ChEBI: Methylcyclohexane is a cycloalkane that is cyclohexane substituted by a single methyl group. It has a role as an aprotic solvent, a plant metabolite and a human metabolite. It is a cycloalkane and a volatile organic compound. It derives from a hydride of a cyclohexane.

• Vorbereitung Methode

  Methylcyclohexane is separated by distillation from crude petroleum oils, and also produced by hydrogenation of toluene, reaction of benzene with methane, or acidic hydrocracking of polycyclic aromatics.

• Synthesis Reference(s)

  Journal of the American Chemical Society, 77, p. 5099, 1955 DOI: 10.1021/ja01624a044
  The Journal of Organic Chemistry, 41, p. 1393, 1976 DOI: 10.1021/jo00870a022

• Allgemeine Beschreibung

  A clear colorless liquid with a petroleum-like odor. Flash point 25°F. Less dense than water and insoluble in water. Vapors heavier than air.

• Air & Water Reaktionen

  Highly flammable. Insoluble in water.

• Reaktivität anzeigen

  Saturated aliphatic hydrocarbons, such as Methylcyclohexane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.

• Hazard

  Flammable, dangerous fire risk. Lowerexplosive limit 1.2% in air. Upper respiratory tractirritant, central nervous system impairment, liverand kidney damage.

• Health Hazard

  Harmful if inhaled or swallowed. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract and skin. Narcotic effects and dermititis.

• Brandgefahr

  Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback containing explosion may occur during fire conditions. Forms explosive mixtures in air.

• Flammability and Explosibility

  Highly flammable

• Sicherheitsprofil

  Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. This material does not cause irritation to the eyes and nose, and, even at the level of 500 ppm, exhbits only a very faint odor. Therefore, it cannot be said to have any warning properties. It is believed to be about three times as toxic as hexane, and has caused death by tetanic spasm in animals. In sublethal concentrations, it causes narcosis and anesthesia. Dangerous fire hazard and moderate explosion hazard when exposed to heat, flame, or oxidzers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

• mögliche Exposition

  Methylcyclohexane is used as a solvent for cellulose derivatives particularly with other solvents; and as an organic intermediate in organic synthesis. A component of jet fuel.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

• Source

  Schauer et al. (1999) reported methylcyclohexane in a diesel-powered medium-duty truck exhaust at an emission rate of 620 μg/km.
  Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of methylcyclohexane was 8.6 mg/kg of pine burned. Emission rates of methylcyclohexane were not measured during the combustion of oak and eucalyptus.
  California Phase II reformulated gasoline contained methylcyclohexane at a concentration of 7.87 mg/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 1.86 and 274 mg/km, respectively (Schauer et al., 2002).

• Environmental Fate

  Biological. May be oxidized by microbes to 4-methylcyclohexanol, which may oxidize to give 4-methylcycloheptanone (Dugan, 1972).
  Photolytic. Based on a photooxidation rate constant 1.04 x 10^-11 cm³/molecule?sec for the reaction of cyclohexane and OH radicals in the atmosphere at 298 K, the estimated lifetime of methylcyclohexane is 13 h (Altshuller, 1991).
  Chemical/Physical. Complete combustion in air produces carbon dioxide and water vapor. Methycyclohexane will not hydrolyze in water because it does not contain a hydrolyzable functional group.
  Complete combustion in air yields carbon dioxide and water. Incomplete combustion also yields carbon monoxide.

• Lager

  Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Methylcyclohexane must be stored to avoid contact withstrong oxidizers, (such as chlorine, bromine, chlorine oxide,nitrates and permanganates), since violent reactions occur.Before entering confined space where this chemical may bepresent, check to make sure that an explosive concentrationdoes not exist. Store in tightly closed containers in a cool,well-ventilated area away from heat. Sources of ignition,such as smoking and open flames, are prohibited wheremethylcyclohexane is handled, used, or stored. Metalcontainers involving the transfer of 5 gallons or more ofmethylcyclohexane should be grounded and bonded. Drumsmust be equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof methylcyclohexane

• Versand/Shipping

  UN2296 Methylcyclohexane, Hazard Class: 3; Labels: 3-Flammable liquid.

• läuterung methode

  Passage through a column of activated silica gel gives material transparent down to 220nm. It can also be purified by passage through a column of activated basic alumina, or by azeotropic distillation with MeOH, followed by washing out the MeOH with H2O, drying and distilling. Methylcyclohexane can be dried with CaSO4, CaH2 or sodium. It has also been purified by shaking with a mixture of conc H2SO4 and HNO3 in the cold, washing with H2O, drying with CaSO4 and fractionally distilling it from potassium. Percolation through a Celite column impregnated with 2,4-dinitrophenylhydrazine (DNPH), phosphoric acid and H2O (prepared by grinding 0.5g DNPH with 6mL 85% H3PO4, then mixing with 4mL of distilled H2O and 10g of Celite) removes carbonyl-containing impurities. [Cowan et al. J Chem Soc 1865 1939, Beilstein 5 III 65, 5 IV 94.]

• Inkompatibilitäten

  Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some plastics, rubber and coatings

• Waste disposal

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Methylcyclohexane Upstream-Materialien And Downstream Produkte

Methylcyclohexan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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