2,3,5,9,10,10a-Hexahydro-10-hydroxy-α-methyl-1H,10bH-benzo[ij]quinolizine-10b-propionic acid methyl ester

2,3,5,9,10,10a-Hexahydro-10-hydroxy-α-methyl-1H,10bH-benzo[ij]quinolizine-10b-propionic acid methyl ester Chemische Eigenschaften,Einsatz,Produktion Methoden

• Beschreibung

  A minor constituent of Lycopodium annotinum, this alkaloid has [α]¹⁸_D+ 125° and yields an ultraviolet spectrum in EtOH having a single absorption maximum at 235 mJ.1. It yields a crystalline picrolonate, m.p. 230-1 °C. The structure has been determined from the mass spectrum and by comparison with other Lycopodium alkaloids.

• Definition

  ChEBI: Lyconnotine is a citraconoyl group.

• Einzelnachweise

  Anet et al., Tetrahedron Lett., 751 (1964)
  Valenta et al., J. Amer. Chem. Soc., 86,2533 (1964)