Goldtribromid

Bezeichnung:Goldtribromid

CAS-Nr10294-28-7

Englisch Name:GOLD(III) BROMIDE

CBNumberCB7173020

SummenformelAuBr3

Molgewicht436.68

MOL-Datei10294-28-7.mol

Synonyma

Goldtribromid

Goldtribromid physikalisch-chemischer Eigenschaften

Schmelzpunkt	160°C (dec.)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
Löslichkeit	H2O: slightly soluble(lit.)
Aggregatzustand	Powder
Farbe	orange to brown
Wasserlöslichkeit	Slightly soluble in water.
Sensitive	moisture sensitive
CAS Datenbank	10294-28-7(CAS DataBase Reference)
EPA chemische Informationen	Gold bromide (AuBr3) (10294-28-7)

Sicherheit

Kennzeichnung gefährlicher	C
R-Sätze:	34
S-Sätze:	26-36/37/39-45
RIDADR	UN 3260 8/PG 3
WGK Germany	3
F	8-10-23
TSCA	Yes
HazardClass	8
PackingGroup	III

Gefahreninformationscode (GHS)

GOLD(III) BROMIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R34:Verursacht Verätzungen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Yellowish-gray mass. Decomposes at approximately 165C. Insoluble in water.
Verwenden
Analysis (testing for alkaloids, spermatic fluid), medicine.
Verwenden
Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.
Definition
Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.
läuterung methode
Purify it by adding pure Br2 to the dark powder, securely stopper the container, warm a little and shake while keeping away from light for ca 48hours. Remove the stopper and place it over NaOH until free Br2 is no longer in the apparatus (48-60hours). The bright yellow needles of the tribromide are stable over NaOH in the dark. It is soluble in H2O and in EtOH where it is slowly reduced. Keep it in a cooled, closed container and protect it from light as decomposition causes free gold to be formed. Aurobromic acid can be obtained by adding the calculated amount of conc HBr to AuBr3 (actually Au2Br6) until all dissolves, whereby the acid crystallises out as HAuBr4.5H2O; a deliquescent solid soluble in EtOH with m ca 27o, and store it as above. [Gibson & Colles J Chem Soc 2411 1931, Burawoy & Gibson J Chem Soc 217 1935, Burawoy & Gibson J Chem Soc 219 1935.]

Goldtribromid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

10294-28-7, GOLD(III) BROMIDE Verwandte Suche:

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