Thiocarbonylchlorid

Bezeichnung:Thiocarbonylchlorid

CAS-Nr463-71-8

Englisch Name:Thiophosgene

CBNumberCB7117651

SummenformelCCl2S

Molgewicht114.98

MOL-Datei463-71-8.mol

Synonyma

Thiocarbonylchlorid

Thiocarbonylchlorid physikalisch-chemischer Eigenschaften

Schmelzpunkt	<25 °C
Siedepunkt	73 °C
Dichte	1.508
Dampfdichte	4 (vs air)
Brechungsindex	n20/D 1.548(lit.)
Flammpunkt	62 °C
storage temp.	2-8°C
Löslichkeit	Chloroform
Aggregatzustand	Liquid
Farbe	A reddish liquid
Wasserlöslichkeit	slow decomposition in cold, fast in hot water
BRN	1633495
Stabilität	Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
CAS Datenbank	463-71-8(CAS DataBase Reference)
NIST chemische Informationen	Carbonothioic dichloride(463-71-8)
EPA chemische Informationen	Thiophosgene (463-71-8)

Sicherheit

Kennzeichnung gefährlicher	T
R-Sätze:	22-23-36/37/38
S-Sätze:	7-9-36/37-45-7/9
RIDADR	UN 2474 6.1/PG 2
WGK Germany	1
RTECS-Nr.	XN2450000
F	19-21
HazardClass	6.1(a)
PackingGroup	II
HS Code	28530090
Giftige Stoffe Daten	463-71-8(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Thiophosgene Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R23:Giftig beim Einatmen.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S7:Behälter dicht geschlossen halten.
S9:Behälter an einem gut gelüfteten Ort aufbewahren.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S7/9:Behälter dicht geschlossen an einem gut gelüfteten Ort aufbewahren.
Chemische Eigenschaften
A clear dark red to reddish-yellow liquid. Sharp, choking odor.
Chemische Eigenschaften
Reddish liquid. Decomposes in water and alcohol; soluble in ether.
Verwenden
Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).
Definition
ChEBI: Thiophosgene is a thiocarbonyl compound and a one-carbon compound.
Allgemeine Beschreibung
A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.
Air & Water Reaktionen
Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.
Reaktivität anzeigen
Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.
Hazard
Toxic by ingestion and inhalation.
Health Hazard
Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.
Sicherheitsprofil
Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.
mögliche Exposition
Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.
Versand/Shipping
UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.
Inkompatibilitäten
Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Thiophosgene Upstream-Materialien And Downstream Produkte

Thiocarbonylchlorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

463-71-8, Thiophosgene Verwandte Suche:

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