D-LEUCROSE Struktur

D-LEUCROSE

Bezeichnung:D-LEUCROSE

CAS-Nr7158-70-5

Englisch Name:D-LEUCROSE

CBNumberCB5423725

SummenformelC12H22O11

Molgewicht342.3

MOL-Datei7158-70-5.mol

D-LEUCROSE physikalisch-chemischer Eigenschaften

Siedepunkt	783.2±60.0 °C(Predicted)
Dichte	1.69±0.1 g/cm3(Predicted)
pka	11.81±0.20(Predicted)

Sicherheit

S-Sätze:	24/25
WGK Germany	3
F	3
HS Code	29329990

Gefahreninformationscode (GHS)

D-LEUCROSE Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung
Leucrose is a ketodisaccharide, the chemical structure of which is D-glucopyranosyl-a(l→5)-D-fructopyranose (it is a bond isomer of sucrose, which is α-D-glycopyranosyl-β(l→2)-D-fructofurano side). It was discovered in 1952 as a natural by-product of the fermentational product of dextran from sucrose by Leuconostoc mesenteroides bacteria. It was also isolated from dextran-produc ing cultures of Streptococcus bovis. It occurs naturally in appre ciable amounts in pollen and honey. Leucrose in honey probably arises from microbial action, since honey saccharase is unable to form leucrose under the conditions of honey maturation. It is present when formed in microbial cultures, in concentrations of 1-3%. Leucrose has a sweet taste but has only between 40-50% of the sweetening power of sucrose.
Leucrose is a reducing sugar and crystallizes as the monohydrate. The a(l→5) glucosidic bond shows considerable resistance to acid hydrolysis, but leucrose is a substrate for the α-glucosidase of yeast and it is hydrolyzed efficiently in the (human) small intestine to glucose and fructose.
Leucrose is not fermented by the acid-forming microbial flora of the human oral cavity into dentally harmful organic acids. Leu crose is also neither an acceptor for nor a donator of glucose, and therefore does not contribute to dextran formation in dental plaque. Leucrose is therefore a non-cariogenic sweetening agent useful for incorporation into low-dental risk foodstuffs.
Leucrose is prepared from sucrose by an enzymic transglycosila tion process. The enzyme involved is α-(l-6)-glycosyl transferase or dextran sucrase. This extracellular enzyme is produced by cul turing Leuconostoc mesenteroides bacteria in a 2% sucrose solu tion. After removal of the bacteria, the enzyme solution is adjusted to the appropriate specific activity and then added to an aqueous solution of one-third sucrose and two-thirds fructose. During trans glycosilation, a glucose molecule is removed from the sucrose and transferred to another freely available fructose molecule by creating an a (l→5) bond, thereby forming leucrose. This reaction contin ues until 85-95% of the sucrose is converted to leucrose. The latter is then separated from the remaining glucose and fructose solution by column-chromatography and is crystallized by appropriate cooling.
The specification of leucrose stipulates a purity of 99.6-99.8%, specific rotation of -7.5, water of crystallization content of 4.5%, melting point of 156-158°C, solubility at 30°C of 64%, relative sweetening power 40-50% (depending on temperature and con centration), and a caloric value of 17 kJ/g.

D-LEUCROSE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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