2,6-Diisopropylanilin

Bezeichnung:2,6-Diisopropylanilin

CAS-Nr24544-04-5

Englisch Name:2,6-Diisopropylaniline

CBNumberCB5349476

SummenformelC12H19N

Molgewicht177.29

MOL-Datei24544-04-5.mol

Synonyma

2,6-Diisopropylanilin

2,6-Diisopropylanilin physikalisch-chemischer Eigenschaften

Schmelzpunkt	-45 °C (lit.)
Siedepunkt	257 °C (lit.)
Dichte	0.94 g/mL at 25 °C (lit.)
Dampfdruck	<0.01 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.532(lit.)
Flammpunkt	255 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
Löslichkeit	<0.2g/l
pka	4.25±0.10(Predicted)
Aggregatzustand	Liquid
Farbe	Clear
Wasserlöslichkeit	<0.20 g/L
BRN	2208763
InChIKey	WKBALTUBRZPIPZ-UHFFFAOYSA-N
LogP	3.18 at 20℃
CAS Datenbank	24544-04-5(CAS DataBase Reference)
NIST chemische Informationen	Benzenamine, 2,6-bis(1-methylethyl)-(24544-04-5)
EPA chemische Informationen	2,6-Diisopropylaniline (24544-04-5)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	52/53-36/37/38
S-Sätze:	61-37/39-26
WGK Germany	2
RTECS-Nr.	BX4025000
TSCA	Yes
HS Code	29214980

Gefahreninformationscode (GHS)

2,6-Diisopropylaniline Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
Clear liquid
Verwenden
2,6-Diisopropylaniline acts as an intermediate used in the production of carbodiimides stabilizers, synthetic resins, antioxidants and active pharmaceutical ingredients. It is also used in the preparation of multitopic Schiff-base ligand precursors and 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It also undergoes condensation reaction with triacetylmethane to get -[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione. Further, it is used to prepare N-heterocyclic carbene complexes for alfa-arylation of acyclic ketones, amination of haloarenes and aqueous Suzuki coupling. In addition to this, it is used in the prepartion of organocatalyst based on naphthalene diimides.
Verwenden
2,6-Diisopropylaniline was used in the preparation of multitopic Schiff-base ligand precursors. It was also used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene.
Verwenden
2,6-Diisopropylaniline is used as intermediate for the manufacture of carbodiimides stabilizers, RIM-PUR, synthetic resins, pesticides, antioxidants, pharmaceuticals and other products.
2,6-Diisopropylaniline may be used in the preparation of multitopic Schiff-base ligand precursors.It may be used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It may be used to prepare N-heterocyclic carbene complexes for α-arylation of acyclic ketones, amination of haloarenes, and aqueous Suzuki coupling.
2,6-Diisopropylaniline may be used in the preparation of organocatalyst based on naphthalene diimides (NDIs).
Reaktionen
2,6-Diisopropylaniline is an amine. It undergoes condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione. 2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).
Allgemeine Beschreibung
2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).

2,6-Diisopropylaniline Upstream-Materialien And Downstream Produkte

2,6-Diisopropylanilin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

24544-04-5, 2,6-Diisopropylaniline Verwandte Suche:

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