Tris[2-chloro-1-(chlormethyl)ethyl]phosphat

Bezeichnung:Tris[2-chloro-1-(chlormethyl)ethyl]phosphat

CAS-Nr13674-87-8

Englisch Name:Tris(1,3-dichloro-2-propyl)phosphate

CBNumberCB5194948

SummenformelC9H15Cl6O4P

Molgewicht430.9

MOL-Datei13674-87-8.mol

Synonyma

Tris[2-chloro-1-(chlormethyl)ethyl]phosphat

Tris[2-chloro-1-(chlormethyl)ethyl]phosphat physikalisch-chemischer Eigenschaften

Schmelzpunkt	-64°C
Siedepunkt	315°C
Dichte	1.512
Dampfdruck	0Pa at 25℃
Brechungsindex	n20/D 1.503
Flammpunkt	249°C
storage temp.	Store at -20°C
Löslichkeit	Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
Aggregatzustand	solid
Wichte	1.518 (20/4℃)
Farbe	Colorless to Almost colorless
Wasserlöslichkeit	<0.1 g/100 mL at 24 ºC
Decomposition	240-280 ºC
Merck	14,9087
Stabilität	Stable. Reacts slowly with aqueous acids and alkalies. May soften plastics.
InChIKey	ASLWPAWFJZFCKF-UHFFFAOYSA-N
LogP	3.69 at 20℃
CAS Datenbank	13674-87-8(CAS DataBase Reference)
NIST chemische Informationen	Tris(1,3-dichloroisopropyl)phosphate(13674-87-8)
EPA chemische Informationen	Tris(1,3-dichloro-2-propyl)phosphate (13674-87-8)

Sicherheit

Kennzeichnung gefährlicher	Xn,N
R-Sätze:	20/21/22-36/37/38-51/53-38-20-40
S-Sätze:	26-36/37/39-61-36/37
RIDADR	UN 3082 9/PG 3
WGK Germany	2
RTECS-Nr.	UB1473000
HazardClass	9
PackingGroup	III
HS Code	29199000
Giftige Stoffe Daten	13674-87-8(Hazardous Substances Data)
Toxizität	LD50 orally in rats: 1.85 g/kg (Piotrowski)

Gefahreninformationscode (GHS)

Tris(1,3-dichloro-2-propyl)phosphate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R38:Reizt die Haut.
R20:Gesundheitsschädlich beim Einatmen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
Tris(1,3-dichloro-2-propyl)phosphate is a clear colorless viscous liquid with a relatively low molecular weight, low water solubility, and low lipophilicity (as indicated by log K_ow).
Verwenden
Tris(1,3-dichloro-2-propyl) Phosphate is a flame retardant present in polyurethane foams.
Verwenden
Tris(1,3-dichloro-2-propyl)phosphate [TDCPP] is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints/coatings, furniture and related products, building/construction materials, fabrics/textiles/leather products, and foam seating and bedding products (EPA, 2012).
It is used extensively as an additive to flexible polyurethane foams (PUFs). Its end uses include molded automotive seating foam (e.g., seat cushions and headrests), slabstock foam in furniture, automotive fabric lining, and car roofing (ECHA, 2013). It is a high production volume chemical.
Definition
ChEBI: Tris(1,3-dichloropropan-2-yl) phosphate is a trialkyl phosphate.
Allgemeine Beschreibung
Clear colorless viscous liquid. Generally a super-cooled liquid at room temperature but may occasionally solidify when held at low temperatures for prolonged periods.
Air & Water Reaktionen
Insoluble in water.
Reaktivität anzeigen
Fyrol FR 2 hydrolyzes slowly when refluxed with an aqueous acid. Under alkaline conditions, Fyrol FR 2 exhibits a slow cleavage. Fyrol FR 2 has plasticizing properties and, as such, may soften or deteriorate certain plastics and elastomers (particularly vinyl-based resin, neoprene and natural rubbers).
Brandgefahr
Fyrol FR 2 is combustible.
Sicherheitsprofil
Moderately toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland POx.
Environmental Fate
A series of studies have been performed to evaluate the environmental fate and bioaccumulation potential of Tris(1,3-dichloro-2-propyl)phosphate (TDCPP).EU concluded that TDCPP is expected to be persistent in water, sediment, sewage sludge, and soil. When emitted to the environment, the EU concluded that TDCPP will likely adsorb to particulate matter, based on its low volatility and relatively high adsorption coefficient. The Henry’s law constant suggests that TDCPP will preferentially partition to water, rather than air. When assessing TDCPP's potential for persistence or bioaccumulation, the EU determined that TDCPP can potentially be persistent or very persistent and that it does not meet the criteria for bioaccumulative or very bioaccumulative compounds.

Tris[2-chloro-1-(chlormethyl)ethyl]phosphat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

13674-87-8, Tris(1,3-dichloro-2-propyl)phosphate Verwandte Suche:

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