TRIS(TRIMETHYLSILYL)SILANE

Bezeichnung:TRIS(TRIMETHYLSILYL)SILANE

CAS-Nr1873-77-4

Englisch Name:TRIS(TRIMETHYLSILYL)SILANE

CBNumberCB5176173

SummenformelC9H28Si4

Molgewicht248.66

MOL-Datei1873-77-4.mol

TRIS(TRIMETHYLSILYL)SILANE physikalisch-chemischer Eigenschaften

Siedepunkt	73 °C/5 mmHg (lit.)
Dichte	0.806 g/mL at 25 °C (lit.)
Brechungsindex	n20/D 1.489(lit.)
Flammpunkt	55 °C
storage temp.	Flammables area
Aggregatzustand	liquid
Farbe	Clear, colourless
Wichte	0.806
Wasserlöslichkeit	Miscible with pentane, ether, toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water.
Hydrolytic Sensitivity	8: reacts rapidly with moisture, water, protic solvents
Sensitive	Light Sensitive
Merck	14,9757
BRN	1923953
CAS Datenbank	1873-77-4(CAS DataBase Reference)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	10-36/37/38
S-Sätze:	16-26-36
RIDADR	UN 1993 3/PG 3
WGK Germany	3
F	10-23
TSCA	No
HazardClass	3
PackingGroup	II
HS Code	29319090

Gefahreninformationscode (GHS)

TRIS(TRIMETHYLSILYL)SILANE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
clear colorless to pale yellow liquid
Verwenden
Reducing and hydrosilyating agent.
Verwenden
Tris(trimethylsilyl)silane) is used in the synthesis of silated alkenes and alkynes. Also used in the preparation of fused quinolines.
Verwenden
Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.
Application
Undergoes exothermic decomposition at >100 °C. Radical-based reducing agent for organic halides, selenides, xanthates and isocyanides and ketones in high yields. Can provide complementary stereoselectivity to tri-n-butyltin hydride in the reduction of gem dihalides. Mild reducing agent in nucleoside chemistry.
Allgemeine Beschreibung
Tris(trimethylsilyl)silane is an organosilicon generally used as a radical reducing agent for xanthates, organic halides, isocyanides, selenides, and acid chlorides. It is also used for hydrosilylation of alkenes, alkynes, and dialkyl ketones.
reaction suitability
reagent type: reductant
läuterung methode
Purify it by fractional distillation and taking the middle cut. Store it under N2 or Ar as it is PYROPHORIC and is an IRRITANT. [Chatgilialoglu et al. J Org Chem 53 3641 1988, Balestri et al. J Org Chem 56 678 1991, Chatgilialoglu Acc Chem Res 25 188 1992, NMR: Gilman et al. J Organomet Chem 4 163 1965.]

TRIS(TRIMETHYLSILYL)SILANE Upstream-Materialien And Downstream Produkte

TRIS(TRIMETHYLSILYL)SILANE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

1873-77-4, TRIS(TRIMETHYLSILYL)SILANE Verwandte Suche:

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