Methyl-3-brombenzoat

Bezeichnung:Methyl-3-brombenzoat

CAS-Nr618-89-3

Englisch Name:Methyl 3-bromobenzoate

CBNumberCB4345734

SummenformelC8H7BrO2

Molgewicht215.04

MOL-Datei618-89-3.mol

Synonyma

Methyl-3-brombenzoat

Methyl-3-brombenzoat physikalisch-chemischer Eigenschaften

Schmelzpunkt	31-33 °C(lit.)
Siedepunkt	127-128 °C15 mm Hg(lit.)
Dichte	1.5313 (rough estimate)
Brechungsindex	1.5575
Flammpunkt	>230 °F
storage temp.	Sealed in dry,Room Temperature
Aggregatzustand	Crystalline Solid or Liquid
Farbe	White to light yellow
Wasserlöslichkeit	Slightly soluble in water.
BRN	1940810
InChIKey	KMFJVYMFCAIRAN-UHFFFAOYSA-N
CAS Datenbank	618-89-3(CAS DataBase Reference)
NIST chemische Informationen	Benzoic acid, 3-bromo-, methyl ester(618-89-3)
EPA chemische Informationen	Benzoic acid, 3-bromo-, methyl ester (618-89-3)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	37/39-26-24/25
WGK Germany	3
TSCA	Yes
HS Code	29163990

Gefahreninformationscode (GHS)

Methyl 3-bromobenzoate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
Methyl 3-bromobenzoate is white to light yellow low melting crystalline
Verwenden
Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.
Verwenden
Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.
Allgemeine Beschreibung
Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K₄[Fe(CN)₆] as a cyanating agent.

Methyl 3-bromobenzoate Upstream-Materialien And Downstream Produkte

Methyl-3-brombenzoat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

618-89-3, Methyl 3-bromobenzoate Verwandte Suche:

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