Divinylbenzol

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Warnung

• Gefahrenhinweise

  H315：Verursacht Hautreizungen.

  H319：Verursacht schwere Augenreizung.

  H411：Giftig für Wasserorganismen, mit langfristiger Wirkung.

• Sicherheit

  P264：Nach Gebrauch gründlich waschen.

  P264：Nach Gebrauch gründlich waschen.

  P273：Freisetzung in die Umwelt vermeiden.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P302+P352：BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

  P305+P351+P338：BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

  P332+P313：Bei Hautreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

Divinylbenzene Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• CHEMISCHE GEFAHREN

  Kann polymerisieren beim Erhitzen unter Feuer- und Explosionsgefahr. Reagiert sehr heftig mit Oxidationsmitteln.

• ARBEITSPLATZGRENZWERTE

  TLV: 10 ppm (als TWA); (ACGIH 2005).
  MAK: IIb (nicht festgelegt, aber Informationen vorhanden) (DFG 2008).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation der Dämpfe.

• INHALATIONSGEFAHREN

  Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen, die Haut und die Atemwege.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen.

• LECKAGE

  Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe.

• R-Sätze Betriebsanweisung:

  R37/38:Reizt die Atmungsorgane und die Haut.
  R41:Gefahr ernster Augenschäden.
  R22:Gesundheitsschädlich beim Verschlucken.

• S-Sätze Betriebsanweisung:

  S7:Behälter dicht geschlossen halten.
  S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
  S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
  S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  S39:Schutzbrille/Gesichtsschutz tragen.

• Beschreibung

  Divinylbenzene exists as o-, m-, and p-isomers. The commercial product contains all 3 isomers, but m-isomer predominates. Usually contains an inhibitor to preventpolymerization. The CAS number for the mixed isomersappears on most regulatory lists.DVB is a pale, straw-colored liquid. Molecularweight= 130.20; Specific gravity (H2O:1) 5 0.93; Boilingpoint= 195-200℃; Freezing/Melting point = 2 66.7to 252℃; Vapor pressure=  0.7 mmHg at 20℃; Flashpoint= 62℃ (cc); 76℃ (oc); Autoignition temperature=469℃. Explosive limits: LEL = 0.7%; UEL= 6.2%.Hazard Identification (based on NFPA-704 M RatingSystem): Health 1, Flammability 2, Reactivity 2. Insolublein water.

• Chemische Eigenschaften

  A water-white to straw colored liquid. Slightly less dense than water and insoluble in water. Flash point below 141°F. Vapors may be toxic. Used in making rubber.

• Verwenden

  Comonomer for preparation of crosslinked polymers in production of ion exchange beads and gel permeation chromatography polystyrene beads; polymerization monomer for synthetic rubber, drying oils, and casting resins

• Verwenden

  Divinylbenzene is used as a reactive monomer in polyester resins and for the synthesis of highly crosslinked macroporous styrene as well as a crosslinking agent. It acts as an intermediate in the production of ion exchange resin. Further, it is used in making rubber, petroleum production and polymeric core shell nanoparticles. In addition, it is used to synthesize monodispersed poly divinylbenzene microspheres.

• Verwenden

  Divinylbenzene is a specialty monomer used primarily to make cross-linked polystyrene resins. The largest use of divinylbenzene (DVB) [CAS: 1321-74-0] is in ion-exchange resins for domestic and industrial water softening. Ion-exchange resins are also used as solid acid catalysts for certain reactions, such as esterification. Divinylbenzene is manufactured by dehydrogenation of diethylbenzene, which is an internal product in the alkylation plant for ethylbenzene production.

• Definition

  ChEBI: 1,2-Divinylbenzene is a member of styrenes.

• Allgemeine Beschreibung

  Divinylbenzene (DVB) consists of a combination of meta and para isomers of DVB and ethylvinylbenzene. It can be used as a monomer for the preparation of linear polydivinylbenzene by anionic polymerization.

• Air & Water Reaktionen

  Flammable. Insoluble in water.

• Reaktivität anzeigen

  Divinylbenzene may react vigorously with strong oxidizing agents. Can react exothermically with reducing agents (such as alkali metals and hydrides) to release gaseous hydrogen. May react exothermically with both acids and bases. May in the presence of various catalysts (such as acids) or initiators undergo exothermic polymerization. Inhibited by presence of an additive. When uninhibited violent polymerization may occur . Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.

• Health Hazard

  Divinylbenzene is an irritant of eyes, nose, and mucous membranes.
  Mild respiratory irritation occurred in workers exposed to 0.4–4ppm divinyl benzene. Mild irritation was also reported from skin and eye contact.

• Brandgefahr

  Divinylbenzene is combustible.

• Flammability and Explosibility

  Not classified

• Sicherheitsprofil

  Mildly toxic by ingestion. An eye irritant. Combustible. When heated to decomposition it emits acrid smoke and irritating fumes.

• mögliche Exposition

  Tumorigen,Mutagen. This compound is used as a monomer for thepreparation of special synthetic rubbers, drying oils, ionexchange resins and casting resins, and in polyester resinmanufacture

• Erste Hilfe

  If Divinylbenzene gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

• Carcinogenicity

  Divinyl benzene was weakly genotoxic in vivo, inducing a dose-dependent increase in sister chromatid exchanges and an increase in the frequency of chromosome aberrations in male mice exposed at concentrations of up to 75ppm for 3 days.
  The 2003 ACGIH threshold limit valuetime- weighted average (TLV-TWA) for divinyl benzene is 10ppm (53mg/m3).

• Lager

  Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with DVB you should be trained on itsproper handling and storage. Before entering confined spacewhere this chemical may be present, check to make sure thatan explosive concentration does not exist. Store in tightlyclosed containers in a cool, well-ventilated area away frommetallic salts (such as ferric and aluminum chlorides) andoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates). Store in tightly closed containers ina cool, well-ventilated area away from heat. Sources of ignition, such as smoking and open flames, are prohibited wherethis chemical is used, handled, or stored in a manner thatcould create a potential fire or explosion hazard. Metal containers involving the transfer of 5 gallons or more of thischemical should be grounded and bonded. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers ofthis chemical.

• Versand/Shipping

  Diethylbenzene requires a shipping label of“FLAMMABLE LIQUID.” It falls in Hazard Class 3 andPacking Group II

• läuterung methode

  Purify divinylbenzene by dissolving in Et2O, shaking with H2O, drying over CaCl2, filtering, evaporating and distilling in vacuo. It polymerises within 2-3days unless 4-tertbutylcatechol (0.05%) is added as stabilizer. [Fries & Bestian Chem Ber 69 715 1936, Beilstein 5 III 1366.]

• Inkompatibilitäten

  Forms explosive mixture with air.Violent reaction with strong oxidizers, metallic salts. Ableto polymerize; add inhibitor and monitor to insure effectivelevels are maintained at all times. May accumulate staticelectrical charges, and may cause ignition of its vapors.

Divinylbenzene Upstream-Materialien And Downstream Produkte

Divinylbenzol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(346)Suppliers

1321-74-0, Divinylbenzene Verwandte Suche: