1-Allyloxy-2,3-epoxy-propan

Bezeichnung:1-Allyloxy-2,3-epoxy-propan

CAS-Nr106-92-3

Englisch Name:Allyl glycidyl ether

CBNumberCB3852688

SummenformelC6H10O2

Molgewicht114.14

MOL-Datei106-92-3.mol

Synonyma

Allyl-2,3-epoxypropylether

1-Allyloxy-2,3-epoxy-propan

2-Propenyloxymethyloxiran

1-Allyloxy-2,3-epoxy-propan physikalisch-chemischer Eigenschaften

Schmelzpunkt	-100 °C
Siedepunkt	154 °C(lit.)
Dichte	0.962 g/mL at 25 °C(lit.)
Dampfdichte	3.9 (vs air)
Dampfdruck	4.7 mm Hg ( 25 °C)
Brechungsindex	n20/D 1.433(lit.)
Flammpunkt	135 °F
storage temp.	Store at <= 20°C.
Löslichkeit	50 g/L (20°C)
Aggregatzustand	Liquid
Farbe	Clear colorless
Wichte	0.962
Wasserlöslichkeit	50 g/L (20 ºC)
FreezingPoint	-100
BRN	105871
Henry's Law Constant	(x 10^-6 atm?m³/mol): 3.83 at 20 °C (approximate - calculated from water solubility and vapor pressure)
Expositionsgrenzwerte	NIOSH REL: TWA 5 ppm (22 mg/m³), STEL 10 ppm (44 mg/m³), IDLH 50 ppm; OSHA PEL: ceiling 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm.
Stabilität	Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air.
InChIKey	LSWYGACWGAICNM-UHFFFAOYSA-N
LogP	0.45 at 25℃
CAS Datenbank	106-92-3(CAS DataBase Reference)
NIST chemische Informationen	Oxirane, [(2-propenyloxy)methyl]-(106-92-3)
EPA chemische Informationen	Allyl glycidyl ether (106-92-3)

Sicherheit

Kennzeichnung gefährlicher	Xn
R-Sätze:	10-20/22-37/38-40-41-43-52/53-62-68
S-Sätze:	24/25-26-36/37/39-61
RIDADR	UN 2219 3/PG 3
OEB	A
OEL	TWA: 5 ppm (22 mg/m3), STEL: 10 ppm (44 mg/m3) [skin]
WGK Germany	3
RTECS-Nr.	RR0875000
Selbstentzündungstemperatur	264 °C
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	29109000
Giftige Stoffe Daten	106-92-3(Hazardous Substances Data)
Toxizität	LD50 orally in Rabbit: 922 mg/kg LD50 dermal Rabbit 2550 mg/kg
IDLA	50 ppm

Gefahreninformationscode (GHS)

Allyl glycidyl ether Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.
CHEMISCHE GEFAHREN
Bildung explosionsfähiger Peroxide wahrscheinlich. Kann leicht polymerisieren. Zersetzung beim Verbrennen unter Bildung giftiger Gase. Reagiert sehr heftig mit starken Oxidationsmitteln, Säuren und Basen.
ARBEITSPLATZGRENZWERTE
TLV: 1 ppm (als TWA); Krebskategorie A4 (nicht klassifizierbar als krebserzeugend für den Menschen); (ACGIH 2005).
MAK: Hautresorption; Sensibilisierung der Haut; Krebserzeugend Kategorie 2; (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation, über die Haut und durch Verschlucken.
INHALATIONSGEFAHREN
Beim Verdampfen bei 20 °C kann schnell eine gesundheitsschädliche Kontamination der Luft eintreten.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
ätzend. Die Flüssigkeit verätzt die Augen, die Haut und die Atmungsorgane. Inhalation des Dampfes kann zu Lungenödem führen (s. Anm.). Akute Exposition kann Depression des Zentralnervensystems verursachen. Exposition kann Bewusstseinstrübung verursachen. ärztliche Beobachtung notwendig.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen und zu Hautsensibilisierung führen. Kann genetische Schäden verursachen. Ist stark fortpflanzungsgefährdend für den Menschen.
LECKAGE
Belüftung. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit viel Wasser wegspülen. Persönliche Schutzausrüstung: Umgebungsluftunabhängiges Atemschutzgerät.
R-Sätze Betriebsanweisung:
R10:Entzündlich.
R20/22:Gesundheitsschädlich beim Einatmen und Verschlucken.
R37/38:Reizt die Atmungsorgane und die Haut.
R40:Verdacht auf krebserzeugende Wirkung.
R41:Gefahr ernster Augenschäden.
R43:Sensibilisierung durch Hautkontakt möglich.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R62:Kann möglicherweise die Fortpflanzungsfähigkeit beeinträchtigen.
R68:Irreversibler Schaden möglich.
S-Sätze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
colourless liquid
Chemische Eigenschaften
Allyl glycidyl ether is a colorless liquid with a strong, sweet odor
Chemische Eigenschaften
Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizers agents, acids, and bases. It may form peroxides in storage if in contact with air.
Physikalische Eigenschaften
Clear, colorless, watery, combustible liquid with a strong, pleasant odor. An odor threshold value of 47 mg/m³ was reported (quoted, Verschueren, 1983).
Verwenden
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered as the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyltrimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane.
Verwenden
Reactive diluent in epoxy resin systems; stabilizer of chlorinated compounds; manufacture of rubber
Verwenden
Resin intermediate, stabilizer of chlorinated compounds, vinyl resins, and rubber.
Definition
The length of time something has existed.
Vorbereitung Methode
AGE is manufactured through the condensation of allyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.
Allgemeine Beschreibung
A colorless liquid with a pleasant odor. Flash point 135°F. Slightly less dense than water and insoluble in water. Hence floats on water. Poisonous by ingestion and mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used to make other chemicals.
Air & Water Reaktionen
Flammable. Insoluble in water.
Reaktivität anzeigen
Allyl glycidyl ether reacts violently with oxidizing agents. Can form peroxides. Polymerizes readily [Handling Chemicals Safely 1980. p.128].
Hazard
Skin, eye, and upper respiratory tract irri- tant, and dermatitis. Questionable carcinogen.
Health Hazard
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Health Hazard
Occupational workers exposed to allyl glycidyl ether develop severe symptoms of poisoning that include, but are not limited to, irritation of the eyes, redness, pain, blurred vision, deep skin burns, respiratory system; causes damage of the mucous membranes, dermatitis, burning sensation, shortness of breath, headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, narcosis, possible hematopoietic and reproductive effects. Acute exposure may cause CNS depression. The major target organs include the eyes, skin, respiratory system, blood, and the reproductive system.
Brandgefahr
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Kontakt-Allergie
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane
Sicherheitsprofil
Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS
Allyl glycidyl ether has an LD50 of 390 mg/kg (mouse, oral) and an LD50 of 1600 mg/kg (rat, oral). In rabbits, the dermal LD50 is 2550 mg/kg. Inhalational toxicity has been estimated: LC50 = 270 ppm (mice, 4 h) and 670 ppm (rats, 8 h)
mögliche Exposition
Used as a solvent and emulsifier; making epoxy resins, chlorinated compounds; and rubber.
Carcinogenicity
In a 2-year inhalation carcinogenicity study in Osborne Mendel rats and B6C3F1 mice (50 of each sex at each exposure level), animals were exposed to concentrations of 0, 5, or 10 ppm AGE, 6 h/day, 5 days/ week. Although occasional respiratory epithelial tumors were observed, the NTP concluded the data provided only equivocal evidence of carcinogenicity in male rats and female mice. No evidence was obtained to support a carcinogenic effect in female rats. Some evidence was provided for a carcinogenic response in male mice, which included three adenomas of the respiratory epithelium, dysplasia in four mice, and focal basal cell hyperplasia of the respiratory epithelium in the nasal passages of seven mice .
Environmental Fate
Biological. Bridié et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C for a period of 5 d. The ThOD for allyl glycidyl ether is 2.11 g/g.
Chemical/Physical. Hydrolysis of the epoxide ring is likely forming 1-allyloxy-2,3- dihydroxypropane (Perez and Osterman-Golkar, 2000).
Lager
Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.
Versand/Shipping
UN2219 Allyl glycidal ether, Hazard Class: 3; Labels: 3-Flammable liquid
Inkompatibilitäten
May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizers or amines may cause fire and explosions.
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Vorsichtsmaßnahmen
During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.

Allyl glycidyl ether Upstream-Materialien And Downstream Produkte

1-Allyloxy-2,3-epoxy-propan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

106-92-3, Allyl glycidyl ether Verwandte Suche:

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