1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol

Bezeichnung:1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol

CAS-Nr55219-65-3

Englisch Name:Triadimenol

CBNumberCB3495832

SummenformelC14H18ClN3O2

Molgewicht295.76

MOL-Datei55219-65-3.mol

Synonyma

1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol

1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol physikalisch-chemischer Eigenschaften

Schmelzpunkt	112-117°
Siedepunkt	465.4±55.0 °C(Predicted)
Dichte	1.2990 (rough estimate)
Dampfdruck	A 6 x l0^-7 Pa (20 °C); B 4 x l0^-7 Pa (20 °C)
Brechungsindex	1.5270 (estimate)
Flammpunkt	2 °C
storage temp.	2-8°C
Löslichkeit	DMSO (Slightly), Methanol (Slightly)
pka	13.29±0.20(Predicted)
Wasserlöslichkeit	A 62 mg l^-1 (20 °C); B 33 mg l^-1(20 °C)
Farbe	White to Off-White
Merck	13,9667
BRN	616470
LogP	2.900
CAS Datenbank	55219-65-3(CAS DataBase Reference)
NIST chemische Informationen	Triadimenol(55219-65-3)
EPA chemische Informationen	Triadimenol (55219-65-3)

Sicherheit

Kennzeichnung gefährlicher	Xn,F,T
R-Sätze:	22-52/53-36-20/21/22-11-23-20/22
S-Sätze:	22-61-36-26-45
RIDADR	2588
WGK Germany	2
RTECS-Nr.	KK2200000
HazardClass	6.1(b)
PackingGroup	III
HS Code	29339900
Giftige Stoffe Daten	55219-65-3(Hazardous Substances Data)
Toxizität	LD50 in male, female rats (mg/kg): 1161, 1105 orally; >5000 dermally, 24-hr; LD50 in quail: >10000 mg/kg (Frohberger)

Gefahreninformationscode (GHS)

Triadimenol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R23:Giftig beim Einatmen.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Beschreibung
Triadimenol is a metabolite of triadimefon , a broad-spectrum chiral triazole fungicide, that is formed by reduction of a carbonyl group to the corresponding alcohol. It is teratogenic, inducing cranial nerve and ganglia abnormalities in a rat post-implantation whole embryo culture model when used at concentrations ranging from 12.5 to 125 μM. In vivo, triadimenol induces embryotoxicity in rats and rabbits when administered orally at doses of 100 and 40 mg/kg, respectively. Embryonic exposure to triadimenol (3-3,000 μg/L) induces embryonic mortality as well as decreases fertility and increases the number of female offspring in medaka fish (O. latipes).
Verwenden
Systemic agricultural fungicide; cereal seed protectant.
Verwenden
β-(4-Chlorophenoxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol is a agricultural fungicide that is systemically active against powdery mildews and rusts of grains.
Verwenden
Triadimenol is used for the control of powdery mildews, rusts and Rhynchosporium in cereals, and also as a seed treatment to control bunt, smut and other cereal diseases. It is also used on vines, hops, coffee, tomatoes, vegetables, fruit, tobacco, sugar cane, ornamentals and other crops, mainly against powdery mildews, rusts and various leaf spot diseases.
Definition
ChEBI: A member of the class of triazoles that is 3,3-dimethyl-1-(1,2,4-triazol-1-yl)butane-1,2-diol substituted at position O1 by a 4-chlorophenyl group. A fungicide for cereals, beet and brassicas used to control a range of diseases including powdery mildew, ru ts, bunts and smuts.
Landwirtschaftliche Anwendung
Fungicide: Triadimenol is used to control seed-and soil-borne diseases and to provide early season control of foliar diseases. It is applied to seeds of barley, corn, oats, rye, sorghum and wheat and also to fruits, vegetables and ornamentals. Registered for use in EU countries . Registered for use in the U.S. U.S. Maximum Allowable Residue Levels for Triadimenol
Handelsname
BAYFIDAN®; BAYFRDAN EW®; BAY KWG 0519®; BAYTAN® SEED TREATMENT; BAYTAN 30® FUNGICIDE; PROTEGE ALLEGIANCE BAYTAN®; SPINNAKER®; SUMMIT®; TRIADIMENOL®; TRIAFOL®; TRIAPHOL®
Stoffwechselwegen
When triadimenol is irradiated by UV light in methanol solution, two major degradation products are identified as 1-(4-chlorophenoxy)-3,3-dimethylbutan-2-one and 1-phenoxy-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan- 2-ol. When a spray deposit on apple leaves is exposed outdoors to natural sunlight, the only product detected is the butanone metabolite. The butanone metabolite has very low fungicidal activity against apple powdery mildew, whereas the butanol metabolite gives some control of infection.
Degradation
When a methanolic solution of triadimenol (1) in borosilicate glass apparatus was irradiated by a medium pressure mercury lamp for 20 days, 50% of the triadimenol was photodegraded. The products identified were 1-(4-chlorophenoxy)-3,3-dimethyl^-1-(1H -1,2,4-triazol^-1-yl)butan-2- one (major product) (2), 4-chlorophenol (3) and 1-phenoxy-3,3-dimethyl- 1-(1H-1,2,4-triazol^-1-yl)butan-2-ol(4 ). When triadimenol was irradiated as a solid deposit, 55% of the parent compound was recovered after 18 days and the same products were identified. Losses may be accounted for by volatilisation or photodegradation (Clark and Watkins, 1986) (Scheme 1). The only major product detected 33 days after triadimenol had been applied to apple tree leaf surfaces exposed to light outdoors was 2.

Triadimenol Upstream-Materialien And Downstream Produkte

1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

55219-65-3, Triadimenol Verwandte Suche:

Send Inquriy