Hexansure

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H302：Gesundheitsschädlich bei Verschlucken.

  H311：Giftig bei Hautkontakt.

  H314：Verursacht schwere Verätzungen der Haut und schwere Augenschäden.

• Sicherheit

  P270：Bei Gebrauch nicht essen, trinken oder rauchen.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P301+P312：BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

  P303+P361+P353：BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.

  P305+P351+P338：BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Hexanoic acid Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  öLIGE, FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• CHEMISCHE GEFAHREN

  Schwache Säure. Reagiert sehr heftig mit Säuren, starken Basenund Oxidationsmitteln.

• ARBEITSPLATZGRENZWERTE

  TLV nicht festgelegt (ACGIH 2005).
  MAK nicht festgelegt (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation des Aerosols und über die Haut.

• INHALATIONSGEFAHREN

  Beim Verdampfen bei 20°C tritt eine gesundheitsschädliche Kontamination der Luft nicht oder nur sehr langsam ein

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen, die Hautund die Atemwege. Verschlucken kann zur Aufnahme in der Lunge führen; Gefahr der Aspirationspneumonie.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  (S. Anm.)

• LECKAGE

  Ausgelaufene Flüssigkeit in abdichtbaren Behältern sammeln. Verschüttete Flüssigkeit mit viel Wasser wegspülen. NICHT in die Kanalisation spülen.

• R-Sätze Betriebsanweisung:

  R34:Verursacht Verätzungen.
  R21:Gesundheitsschädlich bei Berührung mit der Haut.

• S-Sätze Betriebsanweisung:

  S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
  S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  S25:Berührung mit den Augen vermeiden.

• Beschreibung

  Hexanoic acid (also known as Caproci acid), is the carboxylic acid derived from hexane with the general formula C5H11COOH. It is a colorless oily liquid with an odor that is fatty, cheesy, waxy, and like that of goats or other barnyard animals. It is a fatty acid found naturally in various animal fats and oils, and is one of the chemicals that give the decomposing fleshy seed coat of the ginkgo its characteristic unpleasant odor. The primary use of hexanoic acid is in the manufacture of its esters for artificial flavors, and in the manufacture of hexyl derivatives, such as hexylphenols. Hexanoic acid belongs to medium chain triglycerides (MCT) that are widely used as a nutrition supplement that added to foods, drugs and cosmetics.

• Chemische Eigenschaften

  Hexanoic acid is a colourless liquid that has a sickening, sweaty, rancid, sour, sharp, pungent, cheesy, fatty, unpleasant odor reminiscent of copra oil. It exhibits an acrid taste. Hexanoic acid may be prepared by fractionation of the volatile fatty acids of coconut oil.

• Physikalische Eigenschaften

  Hexanoic acid is oily, colorless or slightly yellow, and liquid at room temperature. Odor is that of Limburger cheese. Soluble in alcohol and ether; slightly soluble in water. It is derived from the crude fermentation of butyric acid; or by fractional distillation of natural fatty acids.

• Occurrence

  Hexanoic acid is found in many foods, some of which are tapioca pearl, meat bouillon, pecan nut, and oval-leaf huckleberry. A secondary product of butyric fermentation; reported found in the essential oils of lavender, camphor, palmarosa, lemongrass and Juniperus phoenicea; in a few fruital aromas: apple, currant and strawberry; also identified among the constituents of petitgrain lime oil.

• Verwenden

  Hexanoic acid is used to prepare esters by reacting with alcohols, which finds application in artificial flavors. It is also involved in the production of hexylphenols, hexanoates and caproates. Further, it is used as non-viral gene carrier as well as to protect tomato plants from Botrytis cinerea.

• Definition

  ChEBI: Hexanoic acid is a C6, straight-chain saturated fatty acid. It has a role as a human metabolite and a plant metabolite. It is a straight-chain saturated fatty acid and a medium-chain fatty acid. It is a conjugate acid of a hexanoate.

• synthetische

  hexanoic acid is produced by fractionation of the volatile fatty acids of coconut oil.

• Aroma threshold values

  Detection: 93 ppb to 10 ppm

• Synthesis Reference(s)

  Journal of the American Chemical Society, 99, p. 3184, 1977 DOI: 10.1021/ja00451a064
  The Journal of Organic Chemistry, 57, p. 6173, 1992 DOI: 10.1021/jo00049a024
  Tetrahedron Letters, 11, p. 2679, 1970

• Allgemeine Beschreibung

  Hexanoic acid is an oily carboxylic acid found (as glycerides) in cow’s milk and some vegetable oils. It is a white crystalline solid or colorless to light yellow solution with an unpleasant odor. Insoluble to slightly soluble in water and less dense than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make perfumes.

• Air & Water Reaktionen

  Slightly water soluble.

• Reaktivität anzeigen

  Hexanoic acid is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Hexanoic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions. Hexanoic acid reacts with bases, oxidizing agents and reducing agents.

• Hazard

  Strong irritant to tissue.

• Health Hazard

  Harmful if swallowed, inhaled, or absorbed through skin. Material is extremely destructive to tissue of mucous membranes and upper respiratory tract, eyes and skin. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchia, chemical pneumonitis and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

• Brandgefahr

  Special Hazards of Combustion Products: Irritating vapor may be generated.

• Flammability and Explosibility

  Non flammable

• läuterung methode

  Dry the acid with MgSO4 and fractionally distil it from CaSO4. [Beilstein 2 IV 917.]

• Einzelnachweise

  https://pubchem.ncbi.nlm.nih.gov/compound/hexanoic_acid#section=Toxicological-Information
  https://en.wikipedia.org/wiki/Hexanoic_acid

Hexanoic acid Upstream-Materialien And Downstream Produkte

Hexansure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(490)Suppliers

142-62-1, Hexanoic acid Verwandte Suche: