1-Iodo-3,5-dimethylbenzene

Bezeichnung:1-Iodo-3,5-dimethylbenzene

CAS-Nr22445-41-6

Englisch Name:1-Iodo-3,5-dimethylbenzene

CBNumberCB2135658

SummenformelC8H9I

Molgewicht232.06

MOL-Datei22445-41-6.mol

1-Iodo-3,5-dimethylbenzene physikalisch-chemischer Eigenschaften

Schmelzpunkt	-2.9°C (estimate)
Siedepunkt	92-94 °C3 mm Hg(lit.)
Dichte	1.608 g/mL at 25 °C(lit.)
Brechungsindex	n20/D 1.594(lit.)
Flammpunkt	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
Löslichkeit	Sparingly soluble (0.014 g/L) (25°C), Calc.
Aggregatzustand	Liquid
Wichte	1.608
Farbe	Clear light yellow
Sensitive	Light Sensitive
BRN	2039353
InChIKey	ZLMKEENUYIUKKC-UHFFFAOYSA-N
CAS Datenbank	22445-41-6(CAS DataBase Reference)
NIST chemische Informationen	Benzene, 1-iodo-3,5-dimethyl-(22445-41-6)

Sicherheit

Kennzeichnung gefährlicher	Xi,C
R-Sätze:	36/37/38
S-Sätze:	26-36-37/39
WGK Germany	3
Hazard Note	Irritant
HS Code	29039990

Gefahreninformationscode (GHS)

1-Iodo-3,5-dimethylbenzene Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
clear light yellow liquid
Verwenden
1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethylaniline, an arylamine.
It may be used in the following studies:
- α-Arylation of ketones.
- Copper-catalyzed N-arylation of imidazoles.
- Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile.
- Synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe₂O₄ catalyzed C-O cross-coupling with phenol.
- CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine.
- Copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol.
- As a starting material in the synthesis of biphenyl-3,3′,5,5′-tetracarboxylic acid.
- Radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.
Verwenden
suzuki reaction
Verwenden
1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethyl aniline, an aryl amine, It is also used in the following studies; α-Arylation of ketones, Copper-catalyzed N-arylation of imidazoles, Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile, synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol, CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine, copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. It is also employed as a starting material in the synthesis of biphenyl-3,3?,5,5?-tetracarboxylic acid, radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.
Allgemeine Beschreibung
1-Iodo-3,5-dimethylbenzene (5-Iodo-m-xylene) is an aryl halide. It can be obtained from 5-bromo-m-xylene, via copper-catalyzed halogen exchange reaction, in the presence of NaI or KI in n-BuOH or DMF (solvents). It undergoes reaction with phenol in the presence of CuFe₂O₄nano powder as a recyclable catalyst to afford 1,3-dimethyl-5-phenoxybenzene.

1-Iodo-3,5-dimethylbenzene Upstream-Materialien And Downstream Produkte

1-Iodo-3,5-dimethylbenzene Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

22445-41-6, 1-Iodo-3,5-dimethylbenzene Verwandte Suche:

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