Tricyclo[3.3.1.13,7]decan-1-ol Produkt Beschreibung

1-Adamantanol Struktur
768-95-6
  • CAS-Nr.768-95-6
  • Bezeichnung:Tricyclo[3.3.1.13,7]decan-1-ol
  • Englisch Name:1-Adamantanol
  • Synonyma:Tricyclo[3.3.1.13,7]decan-1-ol
    1-AD-OH;1-ADA-OH;1-Adamantol;ADAMANTANOL;damantol-(1);1-Adamatanol;AKOS BC-0650;1-Admantanol;1-Adamantano;1-ADAMANTANOL
  • CBNumber:CB2135047
  • Summenformel:C10H16O
  • Molgewicht:152.23
  • MOL-Datei:768-95-6.mol
Tricyclo[3.3.1.13,7]decan-1-ol physikalisch-chemischer Eigenschaften
  • Schmelzpunkt: :247 °C (subl.) (lit.)
  • Siedepunkt: :214.73°C (rough estimate)
  • Dichte :0.8544 (rough estimate)
  • Brechungsindex :1.4880 (estimate)
  • Flammpunkt: :240°C
  • storage temp.  :Sealed in dry,Room Temperature
  • pka :15.38±0.20(Predicted)
  • Aggregatzustand :Crystalline Powder or Needles
  • Farbe :White to off-white
  • Wasserlöslichkeit :Soluble in ethanol , methanol, and diethyl ether. Partly miscible in water.
  • Sublimation  :240 ºC
  • BRN  :1903952
  • InChIKey :VLLNJDMHDJRNFK-UHFFFAOYSA-N
  • CAS Datenbank :768-95-6(CAS DataBase Reference)
  • NIST chemische Informationen :1-Adamantanol(768-95-6)
Sicherheit
  • Kennzeichnung gefährlicher :Xi
  • R-Sätze: :36/37/38
  • S-Sätze: :22-24/25-36-26
  • WGK Germany  :3
  • RTECS-Nr. :AU4980000
  • Hazard Note  :Irritant
  • HS Code  :29061900

1-Adamantanol Chemische Eigenschaften,Einsatz,Produktion Methoden

  • R-Sätze Betriebsanweisung: R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
  • S-Sätze Betriebsanweisung: S22:Staub nicht einatmen.
    S24/25:Berührung mit den Augen und der Haut vermeiden.
    S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
    S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
  • Chemische Eigenschaften white to off-white crystalline powder or needles
  • Synthesis Reference(s) Synthetic Communications, 19, p. 2061, 1989 DOI: 10.1080/00397918908052598
    Tetrahedron Letters, 28, p. 1941, 1987 DOI: 10.1016/S0040-4039(00)96015-5
  • läuterung methode If 2-adamantanol is a suspected impurity, then dissolve the substance (10g) in acetone (100mL) and add Jones's reagent [CrO3 (10.3g) in H2O (30mL)], then conc H2SO4 (8.7mL) is added dropwise (turns green in colour) until excess reagent is present (slight red colour). Stir overnight, decant the acetone solution from the Cr salts and adamantan-2-one, dry (Na2SO4) and evaporate to dryness. The residue (ca 7g) is chromatographed through Al2O3 (250g) and washed with 50% *benzene/pet ether (b 40-60o), then 100% Et2O (to remove any adamantan-2-one present) and the 1-adamantanol is then eluted with 5% MeOH in Et2O. The eluate is evaporated, and the residue is recrystallised from pet ether (b 30-60o) at -70o, m 287.2-288.5o. It also crystallises from MeOH and can be sublimed in vacuo. It has characteristic IR, max 3640, 1114, 1086, 982 and 930cm-1. [Schleyer & Nicholas J Am Chem Soc 83 182 1961.] [Beilstein 6 IV 391.] Alternatively, if free from the 2-isomer, dissolve it in tetrahydrofuran, dilute with H2O to precipitate the alcohol. Collect, dry and sublime it in a vacuum at 130o. [Stetter et al. Chem Ber 92 1629 1959.]
1-Adamantanol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Tricyclo[3.3.1.13,7]decan-1-ol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
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768-95-6, 1-Adamantanol Verwandte Suche:
  • TRICYCLO[3.3.1.1(3,7)]DECAN-1-OL
  • TRICYCLO[3.3.1.1]DECAN-1-OL
  • 1-HYDROXYDIAMANTANE
  • 1-HYDROXYADAMANTANE
  • 1-AD-OH
  • 1-ADA-OH
  • 1-ADAMANTANOL
  • 1-Adamantol
  • 1-Adamatanol
  • -Adamantyl alcohol
  • damantol-(1)
  • tricyclo(3.3.1.1(sup3,7))decan-1-ol
  • ADAMANTANOL
  • ADAMANTANOL, 1-
  • ADAMANTAN-1-OL
  • AKOS BC-0650
  • 1-Adamantonal
  • 1-Adamantanol,98%
  • LABOTEST-BB LT00436924
  • ADAMANTANOL, 1-(SG)
  • (1-Adamantyl) alcohol
  • Adamantan-3-ol
  • Hydroxyadamantane
  • 1-Adamantanol,99%
  • Tricyclo[3,3,1,1]3,7 decanol-1
  • adamantan-1-ol(SALTDATA: FREE)
  • 1-AdaMantanol, 99% 5GR
  • 1-ADAMANTANOL FOR SYNTHESIS 10 G
  • Adapalene IMpurity H
  • Adamantan-1-ol, Tricyclo[3.3.1.1~3,7~]decan-1-ol
  • 1-Adamanthanol/Adamantan-1-ol
  • 1-Admantanol
  • 1-Adamantano
  • 1-Adamantanol Vetec(TM) reagent grade, 98%
  • Tricyclo(3.3.1.1(sup 3,7))decan-1-ol (9CI)
  • 1-AdaMantanol ReagentPlus(R), 99%
  • 1 - adaMantane alcohol
  • 1 Adamentanol (768-95-6)
  • 1-Adamantanol &gt
  • 1-Adamantanol fandachem
  • (3s,5s,7s)-adamantan-1-ol
  • 768-95-6
  • C9 to C30
  • Alcohols
  • Building Blocks
  • Oxygen Compounds
  • Organic Building Blocks
  • Adamantanes
  • Alcohols
  • Building Blocks
  • C9 to C10
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • FINE Chemical & INTERMEDIATES
  • Adamantane derivatives
  • Adamantanes
  • Pharmaceutical Raw Materials