3-Mercaptopropionsäure

Bezeichnung:3-Mercaptopropionsäure

CAS-Nr107-96-0

Englisch Name:3-Mercaptopropionic acid

CBNumberCB1852730

SummenformelC3H6O2S

Molgewicht106.14

MOL-Datei107-96-0.mol

Synonyma

3-Mercaptopropionsure

3-Mercaptopropionsäure

3-Mercaptopropionsäure physikalisch-chemischer Eigenschaften

Schmelzpunkt	15-18 °C (lit.)
Siedepunkt	110-111 °C/15 mmHg (lit.)
Dichte	1.218 g/mL at 25 °C (lit.)
Dampfdruck	0.04 mm Hg ( 20 °C)
FEMA	4587 \| 3-MERCAPTOPROPIONIC ACID
Brechungsindex	n20/D 1.492(lit.)
Flammpunkt	201 °F
storage temp.	Store below +30°C.
Löslichkeit	Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
Aggregatzustand	Crystalline Powder, Crystals, and/or Chunks
pka	pK1:;pK2:10.84(SH) (25°C)
Farbe	White
Wichte	1.218
Geruch (Odor)	sulfurous roasted
PH	2 (120g/l, H2O, 20℃)
Explosionsgrenze	1.60%(V)
Geruchsart	sulfurous
Wasserlöslichkeit	soluble
Sensitive	Air Sensitive & Hygroscopic
JECFA Number	1936
BRN	773807
Stabilität	Air Sensitive, Hygroscopic
InChIKey	DKIDEFUBRARXTE-UHFFFAOYSA-N
LogP	-2.3 at 22℃
CAS Datenbank	107-96-0(CAS DataBase Reference)
NIST chemische Informationen	3-Thiolpropanoic acid(107-96-0)
EPA chemische Informationen	3-Mercaptopropanoic acid (107-96-0)

Sicherheit

Kennzeichnung gefährlicher	T
R-Sätze:	25-34-23/24/25
S-Sätze:	7-26-36/37/39-45
RIDADR	UN 2922 8/PG 2
WGK Germany	1
RTECS-Nr.	UF5270000
F	10-13
Selbstentzündungstemperatur	662 °F
TSCA	Yes
HazardClass	8
PackingGroup	III
HS Code	29309070
Giftige Stoffe Daten	107-96-0(Hazardous Substances Data)
Toxizität	LD50 orally in Rabbit: 96 mg/kg

Gefahreninformationscode (GHS)

3-Mercaptopropionic acid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R25:Giftig beim Verschlucken.
R34:Verursacht Verätzungen.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
S-Sätze Betriebsanweisung:
S7:Behälter dicht geschlossen halten.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
clear colourless to yellowish liquid after melting
Verwenden
A compound suitable for amino acid analysis by means of OPA
Verwenden
3-Mercaptopropionic acid is widely used in food and beverage industries as a flavoring agent. It is used in the production of PVC stabilizers, which are used as chain transfer agents in polymerizations. It can be used as primary or secondary, color stabilizer in combination with phenolic antioxidant for polymers. It acts as a sulfide ion equivalent and is utilized in the preparation of diaryl sulfide from aryl iodide.
Definition
ChEBI: A mercaptopropanoic acid that is propanoic acid carrying a sulfanyl group at position 3.
Application
3-Mercaptopropionic acid (3-MPA) is used to produce hydrophilic SAMs, which are terminated with carboxylic acids and can be further functionalized to introduce more complex end groups such as enzymes for biosensor applications. SAMs of 3-MPA are capped on ZnSe quantum dots for the electrochemical detection of dopamine. 3-MPA is used as a capping agent on CdTe quantum dot nanocrystals (QD NCs) for use as labeling materials in biomedical applications. It can also be used to modify the surface of iron oxide nanoparticles (Fe2O3) in the extraction and preconcentration of Al³⁺ and Cr³⁺ ions from different biological samples.
Allgemeine Beschreibung
3-Mercaptopropionic acid (3-MPA) is used as a self-assembled monolayer (SAM) with a thiol and carboxylic groups. It has short carbon chains and is mainly used as a capping agent on a variety of nanoparticles.
Biologische Aktivität
3-Mercaptopropionic acid is a blocking drug that causes an increase in sleep and a decrease in wakefulness. A related finding is that nipecotic acid also increases the time needed for isoflurane to induce loss of consciousness, whereas 3-mercaptopropionic acid decreases anesthesia induction time[1].
Einzelnachweise
[1] Thakkar, M. and R. McCarley. “Neurochemistry of Sleep and Wakefulness: Histamine in the control of sleep–wakefulness.”Basic Neurochemistry (Eighth Edition) (2012).

3-Mercaptopropionic acid Upstream-Materialien And Downstream Produkte

3-Mercaptopropionsäure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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