Bismutchloridoxid

Bezeichnung:Bismutchloridoxid

CAS-Nr7787-59-9

Englisch Name:BISMUTH OXYCHLORIDE

CBNumberCB1489282

SummenformelBiClO

Molgewicht260.43

MOL-Datei7787-59-9.mol

Synonyma

Bismutchloridoxid

Bismutchloridoxid physikalisch-chemischer Eigenschaften

Schmelzpunkt	melts at low red heat [MER06]
Dichte	7.72 g/mL at 25 °C (lit.)
Brechungsindex	2.15
Löslichkeit	H2O: insoluble(lit.)
Aggregatzustand	Powder
Farbe	Very pale brown
Wichte	7.72
Geruch (Odor)	at 100.00?%. odorless
Wasserlöslichkeit	Soluble in HCl, HNO3. Insoluble in water, alcohol.
Merck	14,1263
Solubility Product Constant (Ksp)	pKsp: 30.75
InChIKey	GLQBXSIPUULYOG-UHFFFAOYSA-M
CAS Datenbank	7787-59-9(CAS DataBase Reference)
EPA chemische Informationen	Bismuthine, chlorooxo- (7787-59-9)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	26-36
WGK Germany	2
RTECS-Nr.	EB2700000
TSCA	Yes
HS Code	28274990

Gefahreninformationscode (GHS)

BISMUTH OXYCHLORIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
Bismuth oxychloride is a white Lustorus powder, It is an inorganic white pigment commonly used in foundations, blushes and other color cosmetics. Bismuth oxychloride usually comes in two forms: diamond and pearl finishes. The diamond is shimmery and the pearl is more matte.
Bismuth is the least toxic of its periodic table neighbors like lead, tin, antimony and polonium. Bismuth in itself is not safe for use in cosmetics, and must be refined and combined with other elements to produce bismuth oxychloride.

Bismuth occurs naturally, but in very small amounts. Most of the bismuth produced in the USA is as a by-product from refining lead, tin, copper, silver and gold ores.
Once the bismuth has been harvested, it is further refined through several processes to remove dangerous elements like lead. Then it is chlorinated, which gives us bismuth chloride (BiCl3). It still poses a severe risk at this point, smelling of hydrochloric acid. When bismuth chloride is combined with water, it starts to decompose and part of the chlorine is replaced by oxygen from the water. This process is called hydrolysis. The remaining compound is bismuth, chlorine and oxygen = Bismuth oxychloride.
Physikalische Eigenschaften
White powder or tetragonal crystals; density 7.72 g/cm³; practically insoluble in water, alcohol and acetone; soluble in hydrochloric and nitric acids (with decomposition); Ksp 7.0 x 10-⁹.
Verwenden
bismuth oxychloride is an inorganic color additive. It is used mostly in makeup manufacturing and rarely in skin care formulations. It may also be used for pearlization in cosmetics.
Verwenden
It is used as skin protective's, thickeners, and absorbent agents. It act as a coloring agents in cosmetics.
Verwenden
In face powders; as pigment; manufacture of artificial pearls, dry-cell cathodes.
synthetische
Bismuth oxychloride is made by treating bismuth chloride with water and then drying the white precipitate so formed to expel a molecule of water:
BiCl₃ + 2H₂O → Bi(OH)₂Cl + 2HCl

Bi(OH)₂Cl → BiOCl + H₂O
Also, the compound is prepared by treating a dilute nitric acid solution of bismuth nitrate with sodium chloride.
Allgemeine Beschreibung
Odorless white solid. Sinks in water.
Reaktivität anzeigen
BISMUTH OXYCHLORIDE emits toxic fumes of chloride ion and bismuth when heated to decomposition [USCG, 1999].
Health Hazard
Contact with dust causes mild eye irritation and can cause skin rashes.
Flammability and Explosibility
Not classified

BISMUTH OXYCHLORIDE Upstream-Materialien And Downstream Produkte

Bismutchloridoxid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

7787-59-9, BISMUTH OXYCHLORIDE Verwandte Suche:

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