6-Chlorchinolin

Bezeichnung:6-Chlorchinolin

CAS-Nr612-57-7

Englisch Name:6-CHLOROQUINOLINE

CBNumberCB1334793

SummenformelC9H6ClN

Molgewicht163.6

MOL-Datei612-57-7.mol

Synonyma

6-Chlorchinolin

6-Chlorchinolin physikalisch-chemischer Eigenschaften

Schmelzpunkt	41-43 °C (lit.)
Siedepunkt	126-127 °C/10 mmHg (lit.)
Dichte	1.2108 (rough estimate)
Brechungsindex	1.6110 (estimate)
Flammpunkt	>230 °F
storage temp.	Inert atmosphere,Room Temperature
Aggregatzustand	powder to lump
pka	4.18±0.10(Predicted)
Farbe	White to Light yellow to Light orange
Wasserlöslichkeit	Insoluble in water.
BRN	112963
InChIKey	GKJSZXGYFJBYRQ-UHFFFAOYSA-N
CAS Datenbank	612-57-7(CAS DataBase Reference)
NIST chemische Informationen	Quinoline, 6-chloro-,(612-57-7)
EPA chemische Informationen	Quinoline, 6-chloro- (612-57-7)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	26-37/39
WGK Germany	3
TSCA	Yes
HS Code	29334900

Gefahreninformationscode (GHS)

6-CHLOROQUINOLINE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
beige to brown crystals
Verwenden
6-chloroquinoline is a useful research chemical.
Verwenden
6-Chloroquinoline may be used in the synthesis of 3-methyl-3H-imidazo[4,5-f]quinolin-2-amine. It may be used as catalyst for high yield preparation of ethoxycarbonyl isothiocyanate.
synthetische
All the reactions were carried out in a 50 mL stainless steel autoclave . A mixture of glycerol (1 g, 1 equiv.), aniline (0.58 g, 0.5 equiv.), water (2.5 mL) and W-KIT-6 (100 mg) was charged in to the autoclave simultaneously and finally heated to 200 °C with stirring for 3 h. On completion of the reaction (monitored by TLC), the autoclave was cooled to room temperature and the catalyst was removed by filtration. Ethyl acetate (10 mL) and water (5 mL) were added to the reaction mixture and stirred well for few minutes. The organic layer was dried over anhydrous Na2SO4 and the crude was purified by column chromatography using 60-120 mesh silica with ethylacetate/hexane as eluent to afford 6-chloroquinoline in good yield.
Allgemeine Beschreibung
The standard molar enthalpy of formation of 6-chloroquinoline has been derived from the standard molar enthalpy of combustion and was evaluated in terms of molecular structure. Its arylation reaction with diamine derivatives of adamantanes in the presence of palladium catalyst has been reported to afford N,N′-diaryl derivatives.

6-CHLOROQUINOLINE Upstream-Materialien And Downstream Produkte

6-Chlorchinolin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

612-57-7, 6-CHLOROQUINOLINE Verwandte Suche:

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