Fluazinam

Bezeichnung:Fluazinam

CAS-Nr79622-59-6

Englisch Name:Fluazinam

CBNumberCB1161197

SummenformelC13H4Cl2F6N4O4

Molgewicht465.09

MOL-Datei79622-59-6.mol

Fluazinam physikalisch-chemischer Eigenschaften

Schmelzpunkt	100-102°
Siedepunkt	376.1±42.0 °C(Predicted)
Dichte	1.766±0.06 g/cm3(Predicted)
Dampfdruck	1.5 x 10^-3 Pa (25 °C)
Flammpunkt	2 °C
storage temp.	2-8°C
Löslichkeit	DMF:25.0(Max Conc. mg/mL);53.75(Max Conc. mM) DMSO:25.0(Max Conc. mg/mL);53.75(Max Conc. mM) Ethanol:15.0(Max Conc. mg/mL);32.25(Max Conc. mM) PBS (pH: 7.2):0.25(Max Conc. mg/mL);0.54(Max Conc. mM)
Aggregatzustand	Solid
pka	7.11(at 25℃)
Wasserlöslichkeit	1.7 mg l^-1 (25 °C)
Farbe	Light yellow to Amber to Dark green
Merck	14,4117
BRN	4772672
InChIKey	UZCGKGPEKUCDTF-UHFFFAOYSA-N
LogP	3.560
CAS Datenbank	79622-59-6(CAS DataBase Reference)
EPA chemische Informationen	Fluazinam (79622-59-6)

Sicherheit

Kennzeichnung gefährlicher	T;N,N,T,Xn,F
R-Sätze:	23-41-43-50/53-36-20/21/22-11-38-20-63
S-Sätze:	26-36/37/39-45-60-61-36/37-16-63-57-56-38-28-27-24/25-20/21-13
RIDADR	UN 2811
WGK Germany	3
RTECS-Nr.	UR8085000
HazardClass	6.1
PackingGroup	II
HS Code	29333990
Giftige Stoffe Daten	79622-59-6(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Fluazinam Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R23:Giftig beim Einatmen.
R41:Gefahr ernster Augenschäden.
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Beschreibung
Fluazinam, with a LogP of 3.56, has very low solubility in water (1.7 mgL?1, pH6.8, 25?C) but higher solubilities in organic solvents (e.g., acetone 470 g/L, dichloromethane 330 g/L, ethanol 150 g/L, all at 20 ?C). The active ingredient forms light yellow crystals with an MP of 115 to 117 ?C and has a vp of 1.5 mPa (25 ?C). The compound is stable to acid, alkali, and heat (5).
Chemische Eigenschaften
yellow crystal mp 115 ~ 117°C
Verwenden
Fluazinam is a broad spectrum fungicide. Fluazinam is commonly used for control of Sclerotinia blight and other soilborne pathogens of peanut as well for the control of potato blight.
Verwenden
Fluazinam is a fungicide with a protective action but with little curative or systemic activity. It is used to control grey mould and downy mildew on vines, apple scab, southern blight and white mould on peanuts and Phytophthora infestans and tuber blight on potatoes. It is also used against clubroot on crucifers, rhizomania on sugar beet and mites in apples.
Verwenden
Fluazinam, discovered and developed by ISK, is a highly active fungicide with broad spectrum activity, including soil borne diseases. Furthermore, it has acaricidal activity. Fluazinam is a multi-site contact fungicide that belongs to the pyridinamine family. Fluazinam has launched in several countries since its commercialization in the early 1990's. Now Fluazinam has established a strong presence in potato late blight, soybean white mold or turf fungicide market.
Definition
ChEBI: Fluazinam is a member of the class of aminopyridines that is 2-amino-5-(trifluoromethyl)pyridine in which one of the amino hydrogens is replaced by a 3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl group. A fungicide used to control grey mould, downy mildew and other fungal pathogens. It has a role as an apoptosis inducer, an allergen, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a C-nitro compound, a chloropyridine, an aminopyridine, a secondary amino compound, a member of monochlorobenzenes and a member of (trifluoromethyl)benzenes.
Allgemeine Beschreibung
Fluazinam is a 2,6-dinitroaniline protectant fungicide, which belongs to the pyridinamine group. It can mostly find applications in agriculture.
Hazard
Moderately toxic by ingestion and inhalation. A reproductive hazard.
Landwirtschaftliche Anwendung
Fungicide: Used to control Sclerotinia blight on peanuts and late blight and white mold on potatoes.
Handelsname
FLUAZINAM 50 WP®; FROWNCIDE®; IKF-1216®; ICIA-192®; OMEGA; PP-192®; SHIRLAN®
Kontakt-Allergie
Fluazinam is a pesticide with a broad spectrum of anti fungal activity. It caused sensitization in employees in the tulip bulb industry and in farmers. Fluazinam induced contact dermatitis in a worker in a plant where it was manufactured.
Sicherheitsprofil
Moderately toxic by ingestion and inhalation. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NOx, F-, and Cl-.
Stoffwechselwegen
Fluazinam may typically be applied to crops of potatoes using up to 10 applications each of 150 g ha^-1. Routes of degradation involve ring hydroxylation in aerobic soils and reduction of the nitro groups in flooded soils. A large amount of unextractable residue was observed. In potatoes and rats, important reactions involve the reduction of nitro groups and the formation of conjugates. In plants, the trifluoromethyl substituents are hydrolysed to carboxylic acid groups. Most of the information presented below was taken from an evaluation of the fungicide published by the UK Pesticide Safety Directorate (PSD, 1994).
Degradation
Fluazinam is stable to acid, alkali and heat (PM). The DT₅₀ values for hydrolysis in buffer solutions held in the dark at 22 °C were 42 and 5.6 days at pH 7 and 9, respectively. There was no appreciable hydrolysis at pH 5. The major reaction involved hydrolysis of a trifluoromethyl group to give the nicotinic acid derivative (2). The DT₅₀ values of fluazinam in buffer solutions exposed to natural sunlight were in the range 2-3 days. Up to 11 products were separated but only the major product formed at pH 9, the nicotinic acid derivative (2), was characterised (PED, 1994).

Fluazinam Upstream-Materialien And Downstream Produkte

Fluazinam Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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