Isolan powder(content2%-20%) Struktur

Isolan

Bezeichnung:Isolan

CAS-Nr119-38-0

Englisch Name:Isolan powder(content2%-20%)

CBNumberCB0851761

SummenformelC10H17N3O2

Molgewicht211.26

MOL-Datei119-38-0.mol

Synonyma

1-Isopropyl-3-methylpyrazol-5-yldimethylcarbamat

Isolan

Isolan physikalisch-chemischer Eigenschaften

Siedepunkt	bp0.7 103°; bp2.5 117.5-118°
Dichte	1.07
Brechungsindex	1.4830 (estimate)
CAS Datenbank	119-38-0
EPA chemische Informationen	Isolane (119-38-0)

Sicherheit

Kennzeichnung gefährlicher	T+
R-Sätze:	27/28
S-Sätze:	28-36/37/39-45
RIDADR	2992
HazardClass	6.1(a)
PackingGroup	I
Giftige Stoffe Daten	119-38-0(Hazardous Substances Data)
Toxizität	LD50 in male, female rats (mg/kg): 23, 13 orally; 5.6, 6.2 dermally (Gaines, 1969)

Gefahreninformationscode (GHS)

Isolan powder(content2%-20%) Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R27/28:Sehr giftig bei Berührung mit der Haut und beim Verschlucken.
S-Sätze Betriebsanweisung:
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Liquid. Miscible with water.
Verwenden
Insecticide.
Allgemeine Beschreibung
Colorless liquid. Used as a systemic aphicide in Europe, insecticide. Currently of little commercial interest. Not registered as a pesticide in the U.S.
Reaktivität anzeigen
Isolan powder(content2%-20%) is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
Hazard
Cholinesterase inhibitor.
Health Hazard
Extremely toxic carbamate; exhibits acute,delayed and chronic effects similar toorganophosphates; cholinesterase inhibitor;found to be more toxic to rats bydermal than oral route (Merck 1996); toxicsymptoms include trembling, pinpoint pupils,lacrimation, excessive salivation, sweating,slurring of speech, jerky movements, nausea,vomiting, loss of bladder control, slightblueness of skin, lips, and nail beds, aswell as convulsion, and coma (Gosselin et al.1984); death can occur from respiratoryarrest; oral lethal dose in adult humanestimated to be within the range 0.5–2 g.
LD50 oral (rat): 11 mg/kg
LD50 skin (rat): 5.6 mg/kg.
Health Hazard
Isolan powder(content2%-20%) is classified as extremely toxic. Probable oral lethal dose in humans is 5-50 mg/kg or between 7 drops and 1 teaspoonful for a 150-lb. person. A cholinesterase inhibitor; although it is not an organic phosphate, it resembles that group in action.
Brandgefahr
When heated to decomposition, Isolan powder(content2%-20%) emits toxic fumes of nitrogen oxides.
Sicherheitsprofil
Poison by ingestion, skin contact, and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. An insecticide. When heated to decomposition it emits toxic fumes of NOx. See also CARBAMATES

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