17β,23β-Epoxyveratraman-3β,11β-diol

17β,23β-Epoxyveratraman-3β,11β-diol Chemische Eigenschaften,Einsatz,Produktion Methoden

• Beschreibung

  A steroidal alkaloid of Veratrum album, the base crystallizes as colourless prisms. It has [α]²⁰_D - 126° (c 0.65, pyridine) and - 76.6° (c 0.58, EtOH). The sulphate yields colourless crystals from aqueous EtOH, m.p. 250-3°C (dec.); [α]²⁰_D° - 175° (c 0.22, 75% EtOH) and the acetyl derivative forms prisms from Me2CO with one mole of solvent. The structure has been confirmed by the total synthesis of the alkaloid.

• Einzelnachweise

  Kutney et al., Intrasci. Chem. Rep., 4, 265 (1970)