Salicylaldehydoxim

Bezeichnung:Salicylaldehydoxim

CAS-Nr94-67-7

Englisch Name:Salicylaldoxime

CBNumberCB0112910

SummenformelC7H7NO2

Molgewicht137.14

MOL-Datei94-67-7.mol

Synonyma

Salicylaldehydoxim

Salicylaldehydoxim physikalisch-chemischer Eigenschaften

Schmelzpunkt	57-59 °C 59-61 °C (lit.)
Siedepunkt	251.96°C (rough estimate)
Dichte	1.2528 (rough estimate)
Brechungsindex	1.5030 (estimate)
storage temp.	Sealed in dry,Room Temperature
Löslichkeit	sparingly soluble in water, soluble in ethanol, diethyl ether, acetone, benzene.
Aggregatzustand	Powder
pka	pK1:1.37(＋1);pK2:9.18;pK3:12.11 (25°C)
Farbe	Bordeaux to purple-red
Geruch (Odor)	Odorless
Wasserlöslichkeit	Slightly soluble in water
Merck	14,8327
BRN	1859881
InChIKey	ORIHZIZPTZTNCU-VMPITWQZSA-N
CAS Datenbank	94-67-7(CAS DataBase Reference)
NIST chemische Informationen	Benzaldehyde, 2-hydroxy-, oxime(94-67-7)
EPA chemische Informationen	Benzaldehyde, 2-hydroxy-, oxime (94-67-7)

Sicherheit

Kennzeichnung gefährlicher	Xn,Xi
R-Sätze:	22-36/37/38
S-Sätze:	26-36
WGK Germany	3
RTECS-Nr.	VN5775000
TSCA	Yes
HazardClass	IRRITANT
HS Code	29280000

Gefahreninformationscode (GHS)

Salicylaldoxime Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
off-white to light beige crystalline powder
Verwenden
As a reagent for copper and nickel.
Verwenden
Salicylaldoxime reacts with several metal ions to give intensively coloured complexes which are insoluble in water. The structure of the copper(II), nickel(II) and palladium(II) complexes is shown in Fig. 14 (structure I), and that of the manganese(II), iron(II), cobalt(II) and zinc(II) complexes in Fig. 14 (structure II). The copper(Il) and palladium(II) salicylaldoxime complexes are of importance from an analytical point of view. The complexes precipitated from aqueous media are easily filterable and washable and are weighed after drying at 100°C. The precipitates are of stoichiometric composition.
The outstanding stabilities of the copper(II) and palladium(II) complexes make the reagent suitable for the selective determination of these metal ions. These two complexes form quantitatively at low pH values where the complexes of other metal ions do not exist.
Besides the gravimetric method, salicylaldoxime is also useful in the volumetric, amperometric and nephelometric determinations of copper and palladium.
Salicylaldoxime gives a black precipitate with VOs~ in media containing sulfuric acid; this is soluble in chloroform to give an orange solution. The reaction is specific for vanadium which can thus be detected by this method in the presence of almost all other metals.
In neutral medium salicylaldoxime reacts with iron(III) to give a red complex which is soluble in water. The reaction is utilized for the detection of micro amounts of iron.

Salicylaldoxime Upstream-Materialien And Downstream Produkte

Salicylaldehydoxim Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

94-67-7, Salicylaldoxime Verwandte Suche:

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