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Two basic processes are used commercially to prepare ABS polymers, namely blending and grafting. These processes give rise to materials which are rather different to each other. Of the two processes, grafting is now the more important.
(a) Blending
The products obtained by this method are mechanical blends of styreneacrylonitrile copolymers and acrylonitrile-butadiene rubbers. The preferred method of preparation is by blending latices of the two copolymers and coagulating the mixture. A wide range of products is possible, depending on the composition of each copolymer and the relative amounts of each employed. A typical blend would consist of the following (solids):
70 parts of styrene-acrylonitrile copolymer (70: 30)
40 parts of acrylonitrile-butadiene rubber (35: 65)
It has been found that non-cross-linked acrylonitrile-butadiene rubbers are compatible with styrene-acrylonitrile copolymers and the mixtures show little improvement in impact strength and have low softening points. However, if the rubber is sufficiently cross-linked so as to be not completely soluble in the copolymer then the mixtures have high impact strengths and high softening points. A convenient method of preparing a suitably crosslinked acrylonitrile-butadiene rubber is to take an emulsion polymerization to high conversion; alternatively, a small amount of divinylbenzene can be added to the emulsion recipe. After the two latices have been mixed, coagulation is brought about by the addition of either an acid or a salt. The resulting crumb is washed, filtered, dried, extruded and chopped into granules.
An alternative method of preparing a blend of the two copolymers is by mixing the solids on a two-roll mill. In this case, a non-cross-linked acrylonitrile-butadiene rubber may be used as starting material. The rubber is firstly cross-linked by milling with a peroxide and then the styrene-acrylonitrile copolymer is added.
The physical nature of these blends does not appear to be the same as that of rubber-modified polystyrenes. When this type of ABS polymer is treated with a solvent such as methyl ethyl ketone the sample swells and only partially breaks up; this indicates that rubber networks permeate the styreneacrylonitrile copolymer matrix. When rubber-modified polystyrenes are treated with a solvent such as toluene, complete disintegration into fine particles occurs.
(b) Grafting
In this method of preparing ABS polymers, acrylonitrile and styrene are polymerized in the presence of a polybutadiene latex. A wide range of products is possible, depending on the relative quantities of reactants.
The reaction is carried out at about 50°C. The solid product is then isolated from the latex.
ABS polymers prepared in this way consist of a continuous matrix of styrene-acrylonitrile copolymer, dispersed particles of polybutadiene and a boundary layer of poly butadiene grafted with acrylonitrile and styrene.

acrylonitrile-butadiene-styrene resins are commonly referred to as ABS resins. These materials are thermoplastic resins that are produced by grafting styrene and acrylonitrile onto a diene-rubber backbone. The usually preferred substrate is polybutadiene because of its low glasstransition temperature (just above ?80 °C). Where ABS resin is prepared by suspension or mass polymerization methods, stereospecific diene rubber made by solution polymerization is the preferred diene. Otherwise the diene used normally is a high-gel or cross-linked latex made by a “hot-emulsion” process.

ABS Resins is a strong and durable polymer. It is a chemically resistant resin. It gets easily attacked by polar solvents. It offers greater impact properties and slightly higher heat distortion temperature than HIPS.
It has a low melting temperature making it suitable for processing by 3D printing on an FDM machine.
ABS shows excellent mechanical properties. It is hard and tough in nature and thus delivers good impact strength. It offers a high degree of surface quality. Apart from these characteristics, Acrylonitrile Butadiene Styrene exhibits good electrical insulating properties.
It is an ideal material of choice for various structural applications. This is because of its several physical properties such as:
High rigidity, good weldability, and insulating properties; Good impact resistance, even at low temperatures; Good abrasion and strain resistance; High dimensional stability (Mechanically strong and stable over time); High surface brightness and excellent surface aspect