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7782-44-7

Name Oxygen
CAS 7782-44-7
EINECS(EC#) 231-956-9
Molecular Formula O2
MDL Number MFCD00011434
Molecular Weight 32
MOL File 7782-44-7.mol

Chemical Properties

Definition The most abundant elementon earth, making up about 47% of the earth’s mass,and essential for respiration.
Appearance Oxygen is a colorless odorless gas or a bluish cryogenic liquid.
Melting point  −218 °C(lit.)
Boiling point  −183 °C(lit.)
density  1.429(0℃)
vapor density  1.11 (vs air)
vapor pressure  >760 mmHg at 20 °C
storage temp.  -20°C
solubility  At 20 °C and at a pressure of 101 kPa, 1 volume dissolves in about 32 volumes of water.
form  colorless gas
color  Colorless gas, liquid, or hexagonal crystals
Odor Odorless gas
Stability: Stable. Vigorously supports combustion. Incompatible with phosphorus, organic materials, many powdered metals.
Water Solubility  one vol gas dissolves in 32 volumes H2O (20°C), in 7 volumes alcohol (20°C); soluble other organic liq, usually higher solubility than in H2O [MER06]
Merck  13,7033
Dielectric constant 1.5(-193℃)
History Oxygen, as a gaseous element, forms 21% of the atmosphere by volume from which it can be obtained by liquefaction and fractional distillation. The atmosphere of Mars contains about 0.15% oxygen. The element and its compounds make up 49.2%, by weight, of the Earth’s crust. About two thirds of the human body and nine tenths of water is oxygen. In the laboratory it can be prepared by the electrolysis of water or by heating potassium chlorate with manganese dioxide as a catalyst. The gas is colorless, odorless, and tasteless. The liquid and solid forms are a pale blue color and are strongly paramagnetic. Ozone (O3), a highly active compound, is formed by the action of an electrical discharge or ultraviolet light on oxygen. Ozone’s presence in the atmosphere (amounting to the equivalent of a layer 3 mm thick at ordinary pressures and temperatures) is of vital importance in preventing harmful ultraviolet rays of the sun from reaching the Earth’s surface. There has been recent concern that pollutants in the atmosphere may have a detrimental effect on this ozone layer. Ozone is toxic and exposure should not exceed 0.2 mg/m3 (8-hour time-weighted average — 40-hour work week). Undiluted ozone has a bluish color. Liquid ozone is bluish black, and solid ozone is violet- black. Oxygen is very reactive and capable of combining with most elements. It is a component of hundreds of thousands of organic compounds. It is essential for respiration of all plants and animals and for practically all combustion. In hospitals it is frequently used to aid respiration of patients. Its atomic weight was used as a standard of comparison for each of the other elements until 1961 when the International Union of Pure and Applied Chemistry adopted carbon 12 as the new basis. Oxygen has thirteen recognized isotopes. Natural oxygen is a mixture of three isotopes. Oxygen 18 occurs naturally, is stable, and is available commercially. Water (H2O with 1.5% 18O) is also available. Commercial oxygen consumption in the U.S. is estimated to be 20 million short tons per year and the demand is expected to increase substantially in the next few years. Oxygen enrichment of steel blast furnaces accounts for the greatest use of the gas. Large quantities are also used in making synthesis gas for ammonia and methanol, ethylene oxide, and for oxy-acetylene welding. Air separation plants produce about 99% of the gas, electrolysis plants about 1%. The gas costs 5¢/ft3 ($1.75/cu. meter) in small quantities.
CAS DataBase Reference 7782-44-7(CAS DataBase Reference)
NIST Chemistry Reference Oxygen(7782-44-7)
EPA Substance Registry System 7782-44-7(EPA Substance)

Safety Data

Hazard Codes  O,C
Risk Statements 
R8:Contact with combustible material may cause fire.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R34:Causes burns.
Safety Statements 
S17:Keep away from combustible material .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 1072 2.2
WGK Germany  -
RTECS  RS2060000
4.5-31
HazardClass  2.2
Safety Profile
Human systemic effects by inhalation: cough and other pulmonary changes. Human teratogenic effects by inhalation: developmental abnormalities of the fetal cardovascular system. Mutation data reported. Not toxic as gas. In liquid form it can cause severe "burns" and tissue damage on contact with the slun due to extreme cold. An oxidant. Though itself nonflammable,it is essential to combustion. Even a slight increase in the oxygen content of the air above the normal 21% greatly increases the oxidation or burning rate (and the hazard) of many materials. Exclusion of O2 from the neighborhood of a fire is one of the principal methods of extinguishment. Avoid smoking, flames, electric sparks. Liquid O2 can explode on contact with readdy oxidizable materials, especially at high temperatures. Under the proper condltions of temperature, pressure, and reagent concentration it can react violently with acetaldehyde, acetylene, acetone, secondary alcohols (e.g., 2-propanol, 2-butanol) aluminum, Al(BH4)3, AH3, aluminumtitanium alloys, alkali metals @hum, cesium, potassium, rubidlum, sodlum, potassium), ammonia, ammonia + platinum, asphalt, ccl4, chlorinated hydrocarbons, cyanogen, barium, benzene, 1,4-benzenediol + 1-propanol, benzoic acid, Be(BH4)2, biological materials + ether, BAszBr3, B2H10, diH6, boron tribromide, boron trichloride, bromine + chlorotrifluoroethylene, butane + Ni(CO)4, carbon disulfide, carbon disulfide + mercury + anthracene, carbon monoxide, CsH, calcium, calcium hosphide, copper + hydrogen sulfide, Cl0H14, cyclohexane-l,2-done biskhenylhydrazone), cycl0℃tatetraene, dborane, diboron tetrafluoride, dimethoxymethane, dimethylketene, dimethyl sulfide, diphenyl ethylene, disilane, ethers (e.g., diethyl ether, diisopropyl ether, tetrahydro furan, dtoxane, ethyl ether), fibrous fabrics, fluorine + hydrogen, fuels, germanium, glycerol, halocarbons (e.g., l,l,l-trichloroethane, trichloroethylene, chlorotrifluoroethylene, bromotrifluoroethylene), hydrazine, hydrocarbons (e.g., 1,l-dphenylethylene, gasoline, cyclohexane, ethylene, cumene, pxylene, but-3-yne), hydrocarbons + promoters (e.g., methyl nitrate, nitromethane, ethyl nitrate, tetrafluorohydrazine), hydrogen, hydrogen sulfide, lithiated dalkylnitrosoamines, magnesium, metals, metal hydrides (e.g., sodtum hydride, uranium hydride, lithium h ydride, potassium hydride , rubidium hydride, cesium hydride, magnesium hydride), methane, methoxycycl0℃tatetraene, 4-methoxytoluene7 Ni(CO)4 + butane, nonmetal hydrides (e.g., diborane, tetraborane(lO), phosphine, pentaborane(1 l), pentaborane(9) , decaborane(l4), aluminum tetrahydroborate), oil films, organic matter, (OF2 + H20), phosphorus, phosphorus tribromide, phosphorus trifluoride, phosphorus(IⅡ) oxide, polymers [e.g., foam rubber, neoprene, polytetrafluoroethylene (teflon)], polytetrafluoroethylene + stainless steel, polyurethane, polyvinyl chloride, propylene oxide, K2O2, rhenium, trirhenium nonachloride, rubber + ozone, rubberized fabric, selenium, NaH, sodium hydroxide + tetramethyldsiloxane, strontium, tetracarbonylnickel, tetracarbonylnickel + mercury, tetrafluoroethylene, tetrafluorohydrazine, tetrasilane, titanium and alloys, trisilane, CH2Cl2, oil, paraformaldehyde, wood, charcoal. Compressed O2 is shipped in steel cylinders under hgh pressure. If these containers are broken due to shock or exposed to high temperature, an explosion and fire may result.
Hazardous Substances Data 7782-44-7(Hazardous Substances Data)
Toxicity
OSHA recommends a minimum oxygen concentration of 19.5% for human occupancy.

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