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Hazard Information

Material Safety Data Sheet(MSDS)

Questions And Answer

• Outline

  Ammonium persulfate is white, odorless single crystal, the formula is (NH4) 2S2O8, it has strong oxidation and corrosion, when heated, it decomposes easily, moisture absorption is not easy, it is soluble in water, the solubility increases in warm water, it can hydrolyze into ammonium hydrogen sulfate and hydrogen peroxide in an aqueous solution. The dry product has good stability, storage is easy, and it has the advantage of convenience and safety and so on. When heated to 120 °C, it can decompose, it is easily damped and it can cake in moist air. It is mainly used as an oxidizing agent and the preparation of hydrogen peroxide, potassium persulfate and other persulfate. It can be used as free initiator of polymerization reaction, particularly vinyl chloride emulsion polymerization of polymerizable compound and redox polymerization. It can be used as bleaching agent in grease, soap industry. It can be used to prepare aniline dyes and dye oxidation and electroplating industry, photographic industry and chemical analysis. For food-grade, it can be used as modifier of wheat, brewer's yeast mildew. It can be used as metal etchant, circuit board cleaning and etching, copper and aluminum surface activation, modified starch, pulp and textile bleaching at low temperature and desizing, circulating water purification treatment systems, oxidative degradation of harmful gases, low formaldehyde adhesive stick bound to accelerate, disinfectants, hair dye decolorization.
  Ammonium persulfate is non-flammable, but it can release of oxygen, so it has the role of combustion-supporting, storage environment must be dry and clean, and well-ventilated. People should pay attention to moisture and rain, it should not be transported in rain. Keep away from fire, heat and direct sunlight. It should keep sealed packaging, clear and intact labels. It should be stored separately with flammable or combustible materials, organic compounds, as well as rust, a small amount of metal, and other reducing substances, it should avoid be mixed to prevent the decomposition of ammonium persulfate and cause explosion. ;

• Chemical properties

  It is colorless monoclinic crystal or white crystalline powder. It is soluble in water, the solubility is 58.2g/100ml water at 0℃. ;

• Uses

  It can be used as analytical reagents, photographic fixing agent and reducing agent.
  It can be used as food preservative, oxidizing agent and initiator of high-molecular polymer.
  It can be used as raw material of producting persulfate and hydrogen peroxide in chemical industry, inhibitor of polymerization organic polymer, initiator of during the polymerization of vinyl chloride monomer. It can be used as bleaching agent in grease, soap industry. It can also be used as corrodent in plate metals cutting eclipse and oil extraction in oil industry. For food-grade, it can be used as modifier of wheat, brewer's yeast mildew.
  It can be used for flour modifier (Limited ≤0.3g/kg, the Japanese standard, 1999); Saccharomyces cerevisiae fungicide (limit 0.1%, FAO/WHO, 1984).
  The above information is edited by the chemicalbook of Wang Xiaodong. ;

• Production methods

  It can be derived by the electrolysis of ammonium sulfate and dilute sulfuric acid and then crystallized.
  Electrolytic process Ammonium sulfate and sulfuric acid formulates to form liquid electrolyte, it is decontaminated by electrolysis, HSO4-can discharge and generate peroxydisulfate acidat in the anode, and then reacts with ammonium sulfate to generate ammonium persulfate, ammonium persulfate goes through filtration, crystallization, centrifugal separation, drying to get ammonium persulfate product when the content reaches a certain concentration in the anode.
  Anode reaction: 2HSO4--2e → H2S2O8
  Cathodic reaction: 2H ++ 2e → H2 ↑
  (NH4) 2S2O4 + H2S2O8 → (NH4) 2S2O8 + H2SO4 ;

• Category

  Oxidant ;

• Toxicity grading

  Mid toxicity. ;

• Acute oral toxicity

  Rat LD50: 689 mg/kg; intraperitoneal-rat LD50: 226 mg/kg. ;

• Explosive hazardous characteristics

  It is strong oxidant, it can explode when mixed with reducing agent, sulfur, phosphorus etc; it can explode when be heated, impacted, and meet fire. ;

• Flammability hazard characteristics

  It can decompose of oxygen when high heat; it can generate toxic nitrogen oxides, sulfur oxides and ammonia fumes when heated. ;

• Storage characteristics

  Treasury should have ventilation and low-temperature drying; loading and unloading should be light; it should be stored separately with organic matter, reducing agents, sulfur, phosphorus combustibles. ;

• Extinguishing agent

  Mist of water, sand.;

• Professional standards

  TWA 2 mg/m3. ;

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