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7440-60-0

Name HOLMIUM
CAS 7440-60-0
EINECS(EC#) 231-169-0
Molecular Formula Ho
MDL Number MFCD00011049
Molecular Weight 164.93
MOL File 7440-60-0.mol

Chemical Properties

Definition Metallic element of atomic number 67, group IIIB of the periodic table, one of the rare-earth elements of the yttrium subgroup, aw 164.9303, valence of 3, no stable isotopes.
Appearance grey metal ingot
Melting point  1474 °C
Boiling point  2695 °C
density  8.8 g/mL at 25 °C(lit.)
solubility  soluble in dilute acid solutions
form  ingot
color  Silver-gray
Specific Gravity 8.795
Water Solubility  reacts slowly with H2O, soluble dilute acids [HAW93]
Sensitive  Air & Moisture Sensitive
Merck  13,4747
Exposure limits ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
History The spectral absorption bands of holmium were noticed in 1878 by the Swiss chemists Delafontaine and Soret, who announced the existence of an “Element X.” Cleve, of Sweden, later independently discovered the element while working on erbia earth. Holmium is named after Cleve’s native city. Pure holmia, the yellow oxide, was prepared by Homberg in 1911. Holmium occurs in gadolinite, monazite, and in other rare-earth minerals. It is commercially obtained from monazite, occurring in that mineral to the extent of about 0.05%. It has been isolated by the reduction of its anhydrous chloride or fluoride with calcium metal. Pure holmium has a metallicto bright silver luster. It is relatively soft and malleable, and is stable in dry air at room temperature, but rapidly oxidizes in moist air and at elevated temperatures. Holmium has unusual magnetic properties. Few uses have yet been found for the element. The element, as with other rare earths, seems to have a low acute toxic rating. Natural holmium consists of one isotope 165Ho, which is not radioactive. Holmium has 49 other isotopes known, all of which are radioactive. The price of 99.9% holmium metal is about $20/g.
Uses
Getter in vacuum tubes, research in electrochemistry, spectroscopy.
CAS DataBase Reference 7440-60-0(CAS DataBase Reference)
EPA Substance Registry System Holmium (7440-60-0)

Safety Data

Hazard Codes  C
Risk Statements 
R34:Causes burns.
Safety Statements 
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
RIDADR  UN 3089 4.1/PG 2
WGK Germany  3
1-10
TSCA  Yes
HazardClass  4.1
PackingGroup  II
HS Code  28053090

Hazard Information

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