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7440-53-1

Name EUROPIUM
CAS 7440-53-1
EINECS(EC#) 231-161-7
Molecular Formula Eu
MDL Number MFCD00010992
Molecular Weight 151.96
MOL File 7440-53-1.mol

Chemical Properties

Definition Atomic number 63, one of the lanthanide or rare-earth elements of the cerium subgroup, aw 151.96, valences of 2, 3; two stable isotopes.
Appearance grey ingots
Melting point  822 °C (lit.)
Boiling point  1527 °C (lit.)
density  5.24 g/mL at 25 °C(lit.)
solubility  reacts with H2O
form  ingot
color  Silver/gray
Specific Gravity 5.24
Resistivity 81 μΩ-cm, 20°C
Water Solubility  Reacts with water.
Sensitive  Air & Moisture Sensitive
Merck  13,3937
Exposure limits ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
InChI InChI=1S/Eu
InChIKey OGPBJKLSAFTDLK-UHFFFAOYSA-N
History In 1890 Boisbaudran obtained basic fractions from samarium-gadolinium concentrates that had spark spectral lines not accounted for by samarium or gadolinium. These lines subsequently have been shown to belong to europium. The discovery of Europium is generally credited to Demarcay, who separated the rare earth in reasonably pure form in 1901. The pure metal was not isolated until recent years. Europium is now prepared by mixing Eu2O3 with a 10% excess of lanthanum metal and heating the mixture in a tantalum crucible under high vacuum. The element is collected as a silvery-white metallic deposit on the walls of the crucible. As with other rare-earth metals, except for lanthanum, europium ignites in air at about 150 to 180°C. Europium is about as hard as lead and is quite ductile. It is the most reactive of the rare-earth metals, quickly oxidizing in air. It resembles calcium in its reaction with water. Bastnasite and monazite are the principal ores containing europium. Europium has been identified spectroscopically in the sun and certain stars. Europium isotopes are good neutron absorbers and are being studied for use in nuclear control applications. Europium oxide is now widely used as a phosphor activator and europium-activated yttrium vanadate is in commercial use as the red phosphor in color TV tubes. Europiumdoped plastic has been used as a laser material. With the development of ion-exchange techniques and special processes, the cost of the metal has been greatly reduced in recent years. Natural europium contains two stable isotopes. Thirty-five other radioactive isotopes and isomers are known. Europium is one of the rarest and most costly of the rare-earth metals. It is priced at about $60/g (99.9% pure).
SMILES [Eu]
Uses
Neutron absorber in nuclear control, color-TV phosphors to activate yttrium, phosphors in postagestamp glues to permit electronic recognition of firstclass mail.
CAS DataBase Reference 7440-53-1(CAS DataBase Reference)
EPA Substance Registry System Europium (7440-53-1)

Safety Data

Hazard Codes  F,C
Risk Statements 
R14/15:Reacts violently with water, liberating extremely flammable gases .
R17:Spontaneously flammable in air.
R34:Causes burns.
Safety Statements 
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S7/8:Keep container tightly closed and dry .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
RIDADR  UN 2813 4.3/PG 2
WGK Germany  3
1-10
TSCA  Yes
HazardClass  4.1
PackingGroup  II
HS Code  28053090

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