ChemicalBook CAS DataBase List 6046-93-1

6046-93-1

Name	Cupric acetate monohydrate
CAS	6046-93-1
EINECS(EC#)	205-553-3
Molecular Formula	C4H8CuO5
MDL Number	MFCD00149570
Molecular Weight	199.65
MOL File	6046-93-1.mol

Synonyms

ACETIC ACID, COPPER SALT COPPER(+2)ACETATE MONOHYDRATE COPPER ACETATE COPPER ACETATE MONOHYDRATE COPPER(II) ACETATE COPPER(II) ACETATE-1-HYDRATE COPPER(II) ACETATE HYDRATE COPPER (II) ACETATE, HYDROUS COPPER(II) ACETATE MONOHYDRATE CUPRIC ACETATE CUPRIC ACETATE 1-HYDRATE CUPRIC ACETATE H2O CUPRIC ACETATE, MONOHYDRATE VERDIGRIS Aceticacid,copper(2+)salt,monohydrate Aceticacidcopper(2+)salt,monohydrate Copperdiacetatemonohydrate Kupfer(II)-acetat-hydrat Acetic acid copper(II) salt monohydrate Copper(Ⅱ) acetate monohydrate

Chemical Properties

Appearance	Cupric acetate is a greenish Blue powder or small crystals.
Melting point	115 °C
Boiling point	240 °C
bulk density	1100kg/m3
density	1.88
vapor density	6.9 (vs air)
storage temp.	Store at +5°C to +30°C.
solubility	72g/l
form	Solid
color	Dark Green
Specific Gravity	1.882
Odor	Slight acetic acid odor
PH	5.2-5.5 (20g/l, H2O, 20℃)
PH Range	5.2 - 5.5
Stability:	Stable. Incompatible with oxidizing agents.
Water Solubility	72 g/L (20 ºC)
Hydrolytic Sensitivity	0: forms stable aqueous solutions
Merck	14,2624
BRN	3730548
Exposure limits	ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChI	1S/2C2H4O2.Cu.H2O/c21-2(3)4;;/h21H3,(H,3,4);;1H2/q;;+2;/p-2
InChIKey	NWFNSTOSIVLCJA-UHFFFAOYSA-L
SMILES	O.CC(=O)O[Cu]OC(C)=O
LogP	-0.285 (est)
CAS DataBase Reference	6046-93-1(CAS DataBase Reference)

Safety Data

Symbol(GHS)	GHS05,GHS07,GHS09
Signal word	Danger
Hazard statements	H302-H314-H410
Precautionary statements	P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes	Xn,N,Xi
Risk Statements	R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . less more
Safety Statements	S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S60:This material and/or its container must be disposed of as hazardous waste . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S36:Wear suitable protective clothing . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . less more
RIDADR	UN 3077 9/PG 3
WGK Germany	3
RTECS	AG3500000
TSCA	Yes
HazardClass	9
PackingGroup	III
HS Code	29152900
Storage Class	8B - Non-combustible corrosive hazardous materials
Hazard Classifications	Acute Tox. 4 Oral Aquatic Acute 1 Aquatic Chronic 2 Eye Dam. 1 Skin Corr. 1B

Raw materials And Preparation Products

Hazard Information

Potential Exposure

Cupric acetate is used as a fungicide, as a catalyst for organic reactions; in textile dyeing and as a pigment for ceramics.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a Medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Forms explosive materials with acetylene gas, ammonia, caustic solutions; sodium hypobromite; notromethane. Keep away from chemically active metals; strong acids; nitrates. Decomposes above 240C forming acetic acid fumes

Chemical Properties

Cupric acetate is a greenish Blue powder or small crystals.

Chemical Properties

Dark green small crystal with odour of acetic acid

Waste Disposal

Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill.

General Description

Copper (II) acetate monohydrate is soluble in water and slightly soluble in methanol, diethylether and acetone. It can be synthesized by reacting acetic acid with copper (II) carbonate or copper(II) hydroxide or copper (II) oxide. Large scale commercial production is undertaken by placing copper metal in the presence of air and refluxing acetic acid. As a transition metal acetate, it can be used to form oxide nanoparticles by sonochemical methods.

reaction suitability

reagent type: catalyst
core: copper

Purification Methods

Recystallise it twice from warm dilute acetic acid solutions (5mL/g) by cooling. [Beilstein 2 IV 111.]

Material Safety Data Sheet(MSDS)

Questions And Answer

Spectrum Detail

Well-known Reagent Company Product Information

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6046-93-1

Chemical Properties

Safety Data

Raw materials And Preparation Products

Raw materials

Preparation Products

Hazard Information

Potential Exposure

First aid

Shipping

Incompatibilities

Chemical Properties

Chemical Properties

Waste Disposal

General Description

reaction suitability

Purification Methods

Material Safety Data Sheet(MSDS)

Questions And Answer

Physical Properties

Uses

Preparation

Toxicity

Spectrum Detail

Well-known Reagent Company Product Information

Supplier

Related Products