General Description
Clear colorless liquid with a pleasant odor. Flash point 43°F.
Reactivity Profile
1,2-DICHLOROETHYLENE reacts with alkalis, difluoromethylene, dihypofluorite, and nitrogen tetraoxide. Contact with solid alkalis or their concentrated solutions will cause formation of chloroacetylene, which ignites in air. Avoid contact with copper and copper alloys. Corrosive to metals unless an inhibitor has been added. Oxidation in the presence of concentrated sulfuric acid or a free radical initiator gives chloroacetyl chloride via epoxide intermediates. Incompatible with organic peroxides .
Air & Water Reactions
Highly flammable. Oxidizes in air to form unstable peroxides that may explode spontaneously. Insoluble in water.
Potential Exposure
Primary irritant (w/o allergic reaction).
1,2-Dichloroethylene is used as a solvent for waxes, resins,
and acetylcellulose. It is also used in the extraction of rubber, as a refrigerant; in the manufacture of pharmaceuticals
and artificial pearls; and in the extraction of oils and fats
from fish and meat.
Fire Hazard
This compound is flammable.
First aid
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit
Shipping
UN1150 Dichloroethylene, Hazard Class: 3;
Labels: 3-Flammable liquid.
Incompatibilities
May form explosive mixture with air.
Attacks some plastics, rubber, and coatings. Incompatible
with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.);
contact may cause fires or explosions. Keep away from
alkaline materials, strong bases, strong acids, oxoacids, and
epoxides. Gradual decomposition results in hydrochloric
acid formation in the presence of ultraviolet light or upon
contact with hot metal or other hot surfaces. Reacts with
strong bases; potassium hydroxide; difluoromethylene,
dihypofluoride, nitrogen tetroxide (explosive); or copper
(and its alloys) producing toxic chloroacetylene which is
spontaneously flammable on contact with air. Attacks some
plastics and coatings.
Chemical Properties
1,2-Dichloroethylene exists in three isomers,
sym-, cis-60% and trans-40%. There are variations in toxicity between these two forms. At room temperature, these
chemicals are colorless liquids with a slightly acrid, ethereal odor. The Odor Threshold in air is 17 ppm.
sym-isomer:
Chemical Properties
colourless liquid
Waste Disposal
Incineration, preferably after
mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove
the halo acids produced. Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
Physical properties
Colorless, viscous liquid with a sweet, pleasant odor. Odor threshold concentration is 17 ppm
(quoted, Amoore and Hautala, 1983).
Uses
Solvent for fats, phenol, camphor, etc. Intermediate in synthesis of chlorinated solvents and compounds.
Definition
ChEBI: 1,2-dichloroethene is a member of chloroethenes.
Flammability and Explosibility
Flammable
Environmental Fate
Soil. In a methanogenic aquifer material, trans-1,2-dichloroethylene biodegraded to vinyl
chloride (Wilson et al., 1986). Under anoxic conditions trans-1,2-dichloroethylene, when
subjected to indigenous microbes in uncontaminated sediments, degraded to vinyl chloride
(Barrio-Lage et al., 1986). trans-1,2-Dichloroethylene showed slow to moderate degradation
concomitant with the rate of volatilization in a static-culture flask-screening test (settled domestic
wastewater inoculum) conducted at 25 °C. At concentrations of 5 and 10 mg/L, percent losses
after 4 wk of incubation were 95 and 93, respectively. The amount lost due to volatilization was
26 to 33% after 10 d (Tabak et al., 1981).
Biological. Heukelekian and Rand (1955) reported a 10-d BOD value of 0.05 g/g which is 7.6%
of the ThOD value of 0.66 g/g.
Photolytic. Carbon monoxide, formic and hydrochloric acids were reported to be photooxidation
products (Gay et al., 1976).
Purification Methods
Dry it with MgSO4, and fractionally distil it under CO2. Fractional crystallisation at low temperatures has also been used. [Beilstein 1 IV 709.]
