Chemical Properties
white granules; oxidant; can ignite organic materials; can be prepared by action of chlorine on a solution of LiOH; used as a bleach and an oxidizing agent, sanitizer for swimming pools, cooling water treatment [HAW93] [KIR81] [FMC93]
General Description
A white granular solid or tablets compressed from the granules, with an odor of chlorine. Noncombustible but accelerates the burning of combustible material. Prolonged exposure of closed containers to heat may result in vigorous decomposition and rupture of the container. Used as a dry bleach. Generally toxic. An irritant.
Air & Water Reactions
Soluble in water. Decomposes slowly in water with the evolution of chlorine gas.
Reactivity Profile
LITHIUM HYPOCHLORITE is a powerful oxidizing agent. particularly in the presence of water or at higher temperature as LITHIUM HYPOCHLORITE decomposes to release oxygen and chlorine gases. Forms highly explosive NCl3 on contact with urea or ammonia. When heated or on contact with acids, produces highly toxic fumes of chlorine gas [Sax, 9th ed., 1996, p. 1905].
Health Hazard
Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
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