ChemicalBook CAS DataBase List 13762-51-1

13762-51-1

Name	Potassium borohydride
CAS	13762-51-1
EINECS(EC#)	237-360-5
Molecular Formula	BH4K
MDL Number	MFCD00011396
Molecular Weight	53.94
MOL File	13762-51-1.mol

Synonyms

POTASSIUM BORANATE POTASSIUM BOROHYDRIDE POTASSIUM TETRAHYDRIDOBORATE POTASSIUM TETRAHYDROBORATE Borate(1-), tetrahydro-, potassium Borate(1-),tetrahydro-,potassium Borohydrure de potassium borohydruredepotassium K[BH4] Kaliumborhydrid Kaliumtetrahydridoborat KBH4 Potassium borohydrate potassiumborohydrate potassiumtetrahydroborate(1-) tetrahydro-borate(1-potassium POTASSIUM BOROHYDRIDE, 98+% Potassium borohydride, 99.9% metals basis PotassiumBorohydride>95% Potassium borohydrid

Chemical Properties

Appearance	white crystalline powder
Melting point	500 °C (dec.) (lit.)
bulk density	400kg/m3
density	1.18 g/mL at 25 °C(lit.)
refractive index	1.494
storage temp.	water-free area
solubility	soluble in H2O
form	Powder
color	White
Specific Gravity	1.178
Water Solubility	190 g/L (25 ºC)
Specific Heat Capacity	Cp(crystal):1.78161J/(g·K),at 25℃
Sensitive	Moisture Sensitive
Merck	14,7616
InChI	1S/BH4.K/h1H4;/q-1;+1
InChIKey	ICRGAIPBTSPUEX-UHFFFAOYSA-N
SMILES	[K+].[H][B-]([H])([H])[H]
CAS DataBase Reference	13762-51-1(CAS DataBase Reference)
NIST Chemistry Reference	Potassium tetrahydroborate(13762-51-1)
EPA Substance Registry System	Borate(1-), tetrahydro-, potassium (1:1) (13762-51-1)

Safety Data

Hazard Codes	F,T,C
Risk Statements	R14/15:Reacts violently with water, liberating extremely flammable gases . R24/25:Toxic in contact with skin and if swallowed . R34:Causes burns. R11:Highly Flammable. less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S7/8:Keep container tightly closed and dry . S16:Keep away from sources of ignition-No smoking . less more
RIDADR	UN 1870 4.3/PG 1
WGK Germany	-
RTECS	TS7525000
F	10
TSCA	Yes
REACH Registrations	Active
HazardClass	4.3
PackingGroup	I
HS Code	28500090
Storage Class	4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications	Acute Tox. 3 Oral Eye Dam. 1 Repr. 1B Skin Corr. 1B Water-react 1
Safety Profile	Poison by ingestion. Burns quietly in air. When heated to decomposition it emits toxic fumes of K2O. See also BORON COMPOUNDS and HYDRIDES. less more
Toxicity	LD50 orally in Rabbit: 167 mg/kg LD50 dermal Rabbit 230 mg/kg less more

Raw materials And Preparation Products

Hazard Information

General Description

POTASSIUM BOROHYDRIDE(13762-51-1) is a white crystalline or powdered solid. When exposed to water POTASSIUM BOROHYDRIDE(13762-51-1) may react violently and start a fire. POTASSIUM BOROHYDRIDE(13762-51-1) is toxic by ingestion. POTASSIUM BOROHYDRIDE(13762-51-1) is used to make other chemicals.

Reactivity Profile

A reducing agent. Reacts rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols. Hydrides are incompatible with acids, alcohols, amines, and aldehydes.

Air & Water Reactions

Highly flammable. When exposed to water POTASSIUM BOROHYDRIDE may react violently and start a fire. Produce flammable gases on contact with water. May ignite on contact with water or moist air.

Hazard

Flammable, dangerous fire risk. Toxic by ingestion.

Health Hazard

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.

Fire Hazard

Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.

Chemical Properties

White, crystalline powder. Stable in moist and dry air, stable in vacuum to 500C, decomposed by acids with evolution of hydrogen. Partially soluble in water and ammonia; insoluble in ethers and hydrocarbons.

Uses

Reducing agent; source of H-.

Uses

Source of hydrogen, reducing agent for aldehydes, ketones, acid chlorides; foaming agent for plasticsPotassium borohydride is used as a selective reducing agent for ketones, aldehydes and acid chlorides. It is used as a precursor in the production of chloramphenicol, vitamin A, thiopenicol, atropine and scopolamine. It is used to prepare high dispersive copper nanoparticles by the chemical reduction method using potassium borohydride as a reducing agent.

reaction suitability

reagent type: reductant

Purification Methods

Crystallise it from liquid ammonia. It is slowly hydrolysed by H2O. Its solubility at ~20o in H2O or liquid NH3 is 20%, in MeOH it is 0.7%, in Me2NCHO it is 15% and in MeOH/H2O (1:4) it is 13%. [Jons & Wallbridge Progr Inorg Chem 11 99-231 1970.]

Material Safety Data Sheet(MSDS)

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