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123-73-9

Name Crotonaldehyde
CAS 123-73-9
EINECS(EC#) 204-647-1
Molecular Formula C4H6O
MDL Number MFCD00007003
Molecular Weight 70.09
MOL File 123-73-9.mol

Chemical Properties

Appearance Crotonaldehyde is water-white (turns paleyellow on contact with air) with an irritating, pungent, suffocating odor.
Melting point  −76 °C(lit.)
Boiling point  104 °C(lit.)
density  0.853 g/mL at 20 °C(lit.)
vapor density  2.41 (vs air)
vapor pressure  32 mm Hg ( 20 °C)
refractive index  n20/D 1.437
Fp  48 °F
storage temp.  2-8°C
solubility  water: soluble425.4g/L at 20°C
form  Liquid
color  Clear
Odor Pungent
explosive limit 19.5%
Water Solubility  150 g/L (20 ºC)
Merck  14,2596
BRN  906731
Exposure limits TLV-TWA 6 mg/m3 (2 ppm)(ACGIH); IDLH 400 ppm (NIOSH).
Stability: Light Sensitive
InChIKey MLUCVPSAIODCQM-NSCUHMNNSA-N
LogP 0.600
CAS DataBase Reference 123-73-9(CAS DataBase Reference)
NIST Chemistry Reference Crotonaldehyde(123-73-9)
EPA Substance Registry System 123-73-9(EPA Substance)

Safety Data

Hazard Codes  F,T+,N
Risk Statements 
R11:Highly Flammable.
R24/25:Toxic in contact with skin and if swallowed .
R26:Very Toxic by inhalation.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R50:Very Toxic to aquatic organisms.
R68:Possible risk of irreversible effects.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 1143 6.1/PG 1
WGK Germany  3
RTECS  GP9625000
9-13-23
Autoignition Temperature 320 °F
HazardClass  6.1
PackingGroup  I
HS Code  29121990
Safety Profile
Suspected carcinogen. A poison by ingestion, subcutaneous, and intraperitoneal routes. Mutation data reported. A lachrymating material that is very dangerous to the eyes. Human respiratory system irritant by inhalation. Can cause corneal burns and is irritating to the skin. In case of contact, immediately flush the skin or eyes with water for at least 15 minutes and get medlcal attention. See also ALDEHYDES. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, Con, dry chemical. Incompatible with 1,3-butadiene and oxidizing materials. When heated to decomposition it emits acrid smoke and fumes.
Hazardous Substances Data 123-73-9(Hazardous Substances Data)

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