12245-39-5

Name ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
CAS 12245-39-5
Molecular Formula C13H19O2Rh
MDL Number MFCD00075046
Molecular Weight 310.19
MOL File 12245-39-5.mol
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Chemical Properties

Appearance Orange crystal
Melting point  138-140 °C(lit.)
storage temp.  below 5° C
form  Crystals
color  Yellow to orange
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Sensitive  Air Sensitive
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChI 1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;
InChIKey WDIAJTWVVLHUJU-SUESZSCISA-N
SMILES CC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1

Safety Data

Hazard Codes  Xi
Risk Statements 
Safety Statements 
WGK Germany  3
RTECS  VI9292000
TSCA  No
HS Code  28439000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

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