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122-60-1

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Identification

Name
Glycidyl phenyl ether
CAS
122-60-1
Synonyms
1,2-EPOXY-3-PHENOXYPROPANE
1,2-EPOXYETHYL PHENYL ETHER
1-PHENOXY-2,3-PROPYLENE OXIDE
2,3-EPOXYPROPYL PHENYL ETHER
2-(PHENOXYMETHYL)OXIRANE
GLYCIDYL PHENYL ETHER
PGE
PHENYL 2,3-EPOXYPROPYL ETHER
PHENYL GLYCID ETHER
PHENYL GLYCIDYL ETHER
Phenyl tlycidyl ether
(2,3-epoxypropoxy)-benzen
(2,3-epoxypropoxy)benzene
(phenoxymethyl)-oxiran
(Phenoxymethyl)oxirane
(phenoxymethyl)-Oxirane
1,2-epoxy-3-phenoxy-propan
1-Phenoxy-2,3-epoxypropane
2,3-Epoxy-1-phenoxypropane
2,3-Epoxypropoxybenzene
EINECS(EC#)
204-557-2
Molecular Formula
C9H10O2
MDL Number
MFCD00005133
Molecular Weight
150.17
MOL File
122-60-1.mol

Chemical Properties

Appearance
colourless liquid
Appearance
Phenyl glycidyl ether is a colorless liquid with an unpleasant sweet odor
Melting point 
3.5 °C(lit.)

mp 
3.5 °C(lit.)

Boiling point 
245-247 °C(lit.)

bp 
245-247 °C(lit.)

density 
1.109 g/mL at 25 °C(lit.)

vapor density 
5.2 (vs air)

vapor pressure 
0.03 mm Hg ( 20 °C)

refractive index 
n20/D 1.531

Fp 
>230 °F

storage temp. 
Store below +30°C.
solubility 
2.4g/l
form 
Liquid
color 
Clear colorless to yellow
Stability:
Stable. Incompatible with strong oxidizing agents.
Water Solubility 
2.4 g/L (20 ºC)
InChIKey
FQYUMYWMJTYZTK-UHFFFAOYSA-N
Contact allergens
This monoglycidyl derivative is a reactive diluent in epoxy resins Bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization has been observed in many professions, such as in construction workers, marble workers, ceramic workers, and shoemakers.
CAS DataBase Reference
122-60-1(CAS DataBase Reference)
NIST Chemistry Reference
Oxirane, (phenoxymethyl)-(122-60-1)
EPA Substance Registry System
122-60-1(EPA Substance)

Hazard Information

Chemical Properties
colourless liquid
General Description
Colorless liquid.
Reactivity Profile
PHENYL GLYCIDYL ETHER(122-60-1), an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Air & Water Reactions
Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Slightly soluble in water.
Potential Exposure
PGE is used to increase storage time and stability of halogenated compounds; as a reactive diluent in uncured epoxy resins to reduce the viscosity of the uncured system for ease in casting; adhesive, and laminating applications. NIOSH once estimated that 8000 workers are potentially exposed to PGE.
Fire Hazard
This chemical is probably combustible.
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
Shipping
UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, amines, and curing agents. PGE can presumably form explosive peroxides
Waste Disposal
Concentrated waste containing no peroxides-discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxidesperforation of a container of the waste from a safe distance followed by open burning.

Safety Data

Hazard Codes 
T
Risk Statements 
R45:May cause cancer.
R20:Harmful by inhalation.
R37/38:Irritating to respiratory system and skin .
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R68:Possible risk of irreversible effects.
Safety Statements 
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR 
2810
WGK Germany 
3

RTECS 
TZ3675000

TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29109000
Safety Profile
Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe eye and skin irritant. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a chemical intermediate. See also ETHERS
Hazardous Substances Data
122-60-1(Hazardous Substances Data)

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Material Safety Data Sheet(MSDS)

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